Metal–organic frameworks based on multicarboxylate linkers

H Ghasempour, KY Wang, JA Powell… - Coordination Chemistry …, 2021 - Elsevier
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

Metal-organic frameworks composed of nitro groups: Preparation and applications in adsorption and catalysis

G Lee, DK Yoo, I Ahmed, HJ Lee, SH Jhung - Chemical Engineering …, 2023 - Elsevier
In this review, metal–organic frameworks functionalized with nitro groups (MOF-NO 2 s)
were analyzed, for the first time, in terms of their preparation and applications. MOF-NO 2 s …

Engineering Supramolecular Binding Sites in a Chemically Stable Metal‐Organic Framework for Simultaneous High C2H2 Storage and Separation

K Shao, HM Wen, CC Liang, X Xiao… - Angewandte Chemie …, 2022 - Wiley Online Library
Developing porous materials to overcome the trade‐off between adsorption capacity and
selectivity for C2H2/CO2 separation remains a challenge. Herein, we report a stable HKUST …

Analysis and Refinement of Host–Guest Interactions in Metal–Organic Frameworks

Y Chen, W Lu, M Schröder… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Metal–organic frameworks (MOFs) are a class of hybrid porous materials
characterized by their periodic assembly using metal ions and organic ligands through …

Maximizing acetylene packing density for highly efficient C2H2/CO2 separation through immobilization of amine sites within a prototype MOF

X Zhang, RB Lin, H Wu, Y Huang, Y Ye, J Duan… - Chemical Engineering …, 2022 - Elsevier
For practical separation applications, porous sorbents with high separation performance,
low heat of adsorption, high stability and low production cost are highly desired. A plausible …

Neutron scattering studies of heterogeneous catalysis

X Yu, Y Cheng, Y Li, F Polo-Garzon, J Liu… - Chemical …, 2023 - ACS Publications
Understanding the structural dynamics/evolution of catalysts and the related surface
chemistry is essential for establishing structure–catalysis relationships, where spectroscopic …

Robust lanthanide metal–organic frameworks with “all-in-one” multifunction: Efficient gas adsorption and separation, tunable light emission and luminescence sensing

B Li, JP Dong, Z Zhou, R Wang, LY Wang… - Journal of Materials …, 2021 - pubs.rsc.org
Combining the porous structure and fluorescence properties of metal–organic frameworks
(MOFs) with rational design to realize multifunction application is of great significance from …

Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques

V Bon, E Brunner, A Pöppl… - Advanced Functional …, 2020 - Wiley Online Library
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …

Optimizing Acetylene Sorption through Induced‐fit Transformations in a Chemically Stable Microporous Framework

J Tian, Q Chen, F Jiang, D Yuan… - Angewandte Chemie …, 2023 - Wiley Online Library
Developing practical storage technologies for acetylene (C2H2) is important but challenging
because C2H2 is useful but explosive. Here, a novel metal–organic framework (MOF)(FJI …

Molecular mechanisms behind acetylene adsorption and selectivity in functional porous materials

X Han, S Yang - Angewandte Chemie, 2023 - Wiley Online Library
Since its first industrial production in 1890s, acetylene has played a vital role in
manufacturing a wide spectrum of materials. Although current methods and infrastructures …