Wetting-regulated gas-involving (photo) electrocatalysis: biomimetics in energy conversion
(Photo) electrolysis of water or gases with water to species serving as industrial feedstocks
and energy carriers, such as hydrogen, ammonia, ethylene, propanol, etc., has drawn …
and energy carriers, such as hydrogen, ammonia, ethylene, propanol, etc., has drawn …
Strategic factors to design the next generation of molecular water oxidation catalysts: Lesson learned from ruthenium complexes
Energy conversion through sustainable means is essential to counter global warming and
an urgent solution through a multidisciplinary approach is required. The temperature change …
an urgent solution through a multidisciplinary approach is required. The temperature change …
Promoting photothermal catalytic N2 reduction through dynamic mass transfer and accelerated charge transfer dynamics
T Zeng, H He, K Cheng, Y Hu, P Ding, L Zhang… - Chemical Engineering …, 2024 - Elsevier
The effective adsorption and mass transfer of N 2 at the catalytic active site, along with
efficient photogenerated charge transfer at the interface are the prerequisites for the …
efficient photogenerated charge transfer at the interface are the prerequisites for the …
Electrostatic interactions accelerating water oxidation catalysis via intercatalyst O–O coupling
Intercatalyst coupling has been widely applied in the functional mimics for binuclear synergy
in natural metal enzymes. Herein, we introduce two facile and effective design strategies …
in natural metal enzymes. Herein, we introduce two facile and effective design strategies …
Schottky-like photo/electro-catalytic carbon nanotube composite ultrafiltration membrane reactors
Stimuli-responsive membrane reactors offer advanced strategies towards simultaneous
separation and degradation of persistent organic contaminants, allowing for triggered …
separation and degradation of persistent organic contaminants, allowing for triggered …
Isolation and identification of pseudo seven-coordinate Ru (III) intermediate completing the catalytic cycle of Ru-bda type of water oxidation catalysts
Isolation of RuIII-bda (17-electron specie) complex with an aqua ligand (2-electron donor) is
challenging due to violation of the 18-electron rule. Although considerable efforts have been …
challenging due to violation of the 18-electron rule. Although considerable efforts have been …
Promoting proton transfer and stabilizing intermediates in catalytic water oxidation via hydrophobic outer sphere interactions
The outer coordination sphere of metalloenzyme often plays an important role in its high
catalytic activity, however, this principle is rarely considered in the design of man‐made …
catalytic activity, however, this principle is rarely considered in the design of man‐made …
Insights into the directions to increase turnover frequency and turnover number during photochemical water oxidation with molecular Ru catalysts
A series of four mononuclear water oxidation catalysts (WOCs), denoted as [A2Tpz–RuII], in
which A2 represents two axial monodentate ligands, pyridine (Pyr), 4-picoline (4-Pic) …
which A2 represents two axial monodentate ligands, pyridine (Pyr), 4-picoline (4-Pic) …
Intermolecular O–O Bond Formation between High-Valent Ru–oxo Species
Despite extensive research on water oxidation catalysts over the past few decades, the
relationship between high-valent metal-oxo intermediates and the O–O bond formation …
relationship between high-valent metal-oxo intermediates and the O–O bond formation …
Hydrophobic interactions of Ru-bda-type catalysts for promoting water oxidation activity
The catalytic activity of the bimolecular reaction was affected by many parameters. Although
many efforts have been dedicated to investigate the influence of secondary interactions in …
many efforts have been dedicated to investigate the influence of secondary interactions in …