Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

We have recently reported on several Fe catalysts for N2-to-NH3 conversion that operate at
low temperature (− 78° C) and atmospheric pressure while relying on a very strong …

Despite the critical role Ru and Os complexes have played in the development of transition
metal dinitrogen chemistry, they have not been shown to mediate catalytic N2-to-NH3 …

Among the transition metals, copper-based catalyst systems enable the widest range of N-
containing reagents in C–H amination to allow for the direct incorporation of versatile N …

While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …

The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …

A new and convenient method for the construction of sulfonamides via a copper-catalyzed
oxidative coupling between sodium sulfinates and amines with 1 atm O2 or DMSO as the …

Catalytic CÀH amination is an attractive strategy to prepare CÀN bonds without the need for
a pre-functionalized site.[1–3] This approach offers substantial opportunities to streamline …

A series of Cu (I)− amido complexes both lacking ancillary ligands and containing 1, 10-
phenanthroline (phen) as ancillary ligand have been prepared. These complexes react with …