Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Ligand design in ligand‐protected gold nanoclusters

B Zhang, J Chen, Y Cao, OJH Chai, J Xie - Small, 2021 - Wiley Online Library
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …

[HTML][HTML] Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Three-orders-of-magnitude variation of carrier lifetimes with crystal phase of gold nanoclusters

M Zhou, T Higaki, G Hu, MY Sfeir, Y Chen, D Jiang… - Science, 2019 - science.org
We report a three-orders-of-magnitude variation of carrier lifetimes in exotic crystalline
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …

The critical number of gold atoms for a metallic state nanocluster: resolving a decades-long question

M Zhou, X Du, H Wang, R Jin - ACS nano, 2021 - ACS Publications
Probing the transition from a metallic state to a molecular state in gold nanoparticles is
fundamentally important for understanding the origin of surface plasmon resonance and the …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J Xie - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Chirality and surface bonding correlation in atomically precise metal nanoclusters

Y Li, T Higaki, X Du, R Jin - Advanced Materials, 2020 - Wiley Online Library
Chirality is ubiquitous in nature and occurs at all length scales. The development of
applications for chiral nanostructures is rising rapidly. With the recent achievements of …