Circular dichroism based chirality sensing with supramolecular host–guest chemistry

M Quan, XY Pang, W Jiang - Angewandte Chemie, 2022 - Wiley Online Library
Optical methods are promising to address the ever‐increasing demands for chirality analysis
in drug discovery and related fields because they are amenable to high‐throughput …

Circularly polarized luminescence from chiral macrocycles and their supramolecular assemblies

T Li, X Zhu, G Ouyang, M Liu - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Circularly polarized luminescence (CPL) materials have attracted significant attention in
recent years owing to their potential application prospects in advanced display technologies …

Chemistry and properties of indolocarbazoles

T Janosik, A Rannug, U Rannug, N Wahlström… - Chemical …, 2018 - ACS Publications
The indolocarbazoles are an important class of nitrogen heterocycles which has evolved
significantly in recent years, with numerous studies focusing on their diverse biological …

Circular dichroism sensing: Strategies and applications

JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes

LL Wang, Z Chen, WE Liu, H Ke… - Journal of the …, 2017 - ACS Publications
Chiral epoxides are important intermediates in chemistry and biology. The high-throughput
screening of asymmetric epoxidation conditions requires fast determination of the absolute …

A Self‐Assembled Cage for Wide‐Scope Chiral Recognition in Water

G Wu, Y Chen, S Fang, L Tong, L Shen… - Angewandte Chemie …, 2021 - Wiley Online Library
Herein, we report the self‐assembly of an anionic homochiral octahedral cage by
condensing six Ga3+ cations and four trisacylhydrazone ligands. The robust nature of the …

Fluorescence detected circular dichroism (FDCD) for supramolecular host–guest complexes

A Prabodh, Y Wang, S Sinn, P Albertini, C Spies… - Chemical …, 2021 - pubs.rsc.org
Fluorescence-detected circular dichroism (FDCD) spectroscopy is applied for the first time to
supramolecular host–guest and host–protein systems and compared to the more known …

Chiroptical asymmetric reaction screening via multicomponent self-assembly

ZA De los Santos, C Wolf - Journal of the American Chemical …, 2016 - ACS Publications
Self-assembly of a stereodynamic phosphine ligand, Pd (II), and a chiral amine, amino
alcohol, or amino acid generates characteristic UV and CD signals that can be used for …

Chirality sensing of terpenes, steroids, amino acids, peptides and drugs with acyclic cucurbit [n] urils and molecular tweezers

A Prabodh, D Bauer, S Kubik, P Rebmann… - Chemical …, 2020 - pubs.rsc.org
Achiral chromophoric hosts, ie acyclic cucurbit [n] urils and molecular tweezers, were found
to respond with characteristic Circular Dichroism (CD) spectra to the presence of micromolar …

Extreme stabilization and redox switching of organic anions and radical anions by large-cavity, CH hydrogen-bonding cyanostar macrocycles

CR Benson, EM Fatila, S Lee, MG Marzo… - Journal of the …, 2016 - ACS Publications
Encapsulation of unstable guests is a powerful way to enhance their stability. The lifetimes of
organic anions and their radicals produced by reduction are typically short on account of …