o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

J Shi, L Li, Y Li - Chemical Reviews, 2021 - ACS Publications
Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

Bottom-up supramolecular assembly in two dimensions

I Insua, J Bergueiro, A Méndez-Ardoy… - Chemical …, 2022 - pubs.rsc.org
The self-assembly of molecules in two dimensions (2D) is gathering attention from all
disciplines across the chemical sciences. Attracted by the interesting properties of two …

Self-healing high strength and thermal conductivity of 3D graphene/PDMS composites by the optimization of multiple molecular interactions

H Yu, Y Feng, L Gao, C Chen, Z Zhang… - Macromolecules, 2020 - ACS Publications
Thermally conductive, robust, but self-healable polymer/carbon nanocomposites are the
research focus in functional materials. However, the trade-off between molecular interaction …

Triptycenyl Sulfide: A Practical and Active Catalyst for Electrophilic Aromatic Halogenation Using N-Halosuccinimides

Y Nishii, M Ikeda, Y Hayashi, S Kawauchi… - Journal of the …, 2019 - ACS Publications
A Lewis base catalyst Trip-SMe (Trip= triptycenyl) for electrophilic aromatic halogenation
using N-halosuccinimides (NXS) is introduced. In the presence of an appropriate activator …

End-group chemistry and junction chemistry in polymer science: past, present, and future

J Kim, HY Jung, MJ Park - Macromolecules, 2020 - ACS Publications
The current goal in functional polymeric material research is the preparation of polymers
with high-fidelity nanoscale self-assembled structures and advanced functionality. Thus …

Triptycene-based ladder polymers with one-handed helical geometry

T Ikai, T Yoshida, K Shinohara… - Journal of the …, 2019 - ACS Publications
Here we report an efficient synthesis of optically active ladder-type molecules and polymers
through intramolecular cyclization of chiral triptycenes containing bis [2-(4-alkoxyphenyl) …

Supramolecular scaffold–directed two-dimensional assembly of pentacene into a configuration to facilitate singlet fission

M Fukumitsu, T Fukui, Y Shoji, T Kajitani, R Khan… - Science …, 2024 - science.org
Molecular assemblies featuring two-dimensionality have attracted increasing attention,
whereas such structures are difficult to construct simply relying on spontaneous molecular …

Triptycene tripods for the formation of highly uniform and densely packed self-assembled monolayers with controlled molecular orientation

F Ishiwari, G Nascimbeni, E Sauter… - Journal of the …, 2019 - ACS Publications
When employing self-assembled monolayers (SAMs) for tuning surface and interface
properties, organic molecules that enable strong binding to the substrate, large-area …

Overcoming the entropy of polymer chains by making a plane with terminal groups: a thermoplastic PDMS with a long-range 1D structural order

Y Chen, F Ishiwari, T Fukui, T Kajitani, H Liu… - Chemical …, 2023 - pubs.rsc.org
Due to its unique physical and chemical properties, polydimethylsiloxane (PDMS) is widely
used in many applications, in which covalent cross-linking is commonly used to cure the …

Highly Ordered Supramolecular Materials of Phase‐Separated Block Molecules for Long‐Range Exciton Transport

MHC van Son, AM Berghuis, BFM de Waal… - Advanced …, 2023 - Wiley Online Library
Efficient energy transport over long distances is essential for optoelectronic and light‐
harvesting devices. Although self‐assembled nanofibers of organic molecules are shown to …