Lanthanide complexes for luminescence-based sensing of low molecular weight analytes

ML Aulsebrook, B Graham, MR Grace… - Coordination Chemistry …, 2018 - Elsevier
Recent developments (2012 and onwards) in the design and application of luminescent
lanthanide-based complexes for chemical sensing are reviewed. Sensors for a variety of …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

Downconversion materials for perovskite solar cells

R Datt, S Bishnoi, D Hughes, P Mahajan, A Singh… - Solar …, 2022 - Wiley Online Library
Perovskite solar cells (PSCs) have made game‐changing progress in the last decade and
reached a power conversion efficiency (PCE) of up to 25%. Furthermore, the development of …

Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets

S Mondal, A Lunghi - Journal of the American Chemical Society, 2022 - ACS Publications
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Highly emitting near-infrared lanthanide “encapsulated sandwich” metallacrown complexes with excitation shifted toward lower energy

ER Trivedi, SV Eliseeva, J Jankolovits… - Journal of the …, 2014 - ACS Publications
Near-infrared (NIR) luminescent lanthanide complexes hold great promise for practical
applications, as their optical properties have several complementary advantages over …

Tuning the luminescence efficiency by perfluorination of side chains in Eu 3+ complexes with β-diketones of the thiophene series

EA Varaksina, MA Kiskin, KA Lyssenko… - Physical Chemistry …, 2021 - pubs.rsc.org
A series of europium and gadolinium complexes comprising a β-diketone moiety modified
with a fluorinated side-group and thiophene ring have been designed and synthesized and …

Sparkle/PM7 lanthanide parameters for the modeling of complexes and materials

JDL Dutra, MAM Filho, GB Rocha… - Journal of chemical …, 2013 - ACS Publications
The recently published Parametric Method number 7, PM7, is the first semiempirical method
to be successfully tested by modeling crystal structures and heats of formation of solids. PM7 …

DNA as a target for lanthanide (III) complexes influence

R Jastrząb, M Nowak, M Skrobańska, A Tolińska… - Coordination Chemistry …, 2019 - Elsevier
Despite the rapid development of modern methods of cancer treatments, chemotherapy is
still one of the most important, and sometimes, the only one method of therapy. The …

A polymorphic lanthanide complex as selective Co2+ sensor and luminescent timer

CH Zeng, XT Meng, SS Xu, LJ Han, S Zhong… - Sensors and Actuators B …, 2015 - Elsevier
A rarely reported polymorphic lanthanide complex is prepared by acetylacetone (acac)
tuning method. Luminescence properties of 1 are studied. Interestingly, 1 is proved to be a …

A luminogenic lanthanide-based probe for the highly selective detection of nanomolar sulfide levels in aqueous samples

ML Aulsebrook, S Biswas, FM Leaver… - Chemical …, 2017 - pubs.rsc.org
A bimetallic terbium (III)/copper (II) complex (Tb-1· Cu2+) for the time-gated luminescent
detection of hydrogen sulfide in aqueous samples is reported. The probe shows excellent …