Structures of Organonitrogen—Lithium Compounds: Recent Patterns and Perspectives in Organolithium Chemistry

K Gregory, PVR Schleyer, R Snaith - Advances in inorganic chemistry, 1991 - Elsevier
Publisher Summary This chapter discusses the current patterns and perspectives in
organolithium chemistry, including the structures of organonitrogenlithium (N-Li) …

Meldola Medal Lecture. Ring-stacking and ring-laddering in organonitrogenlithium compounds: The development of concepts with wide applicability throughout …

RE Mulvey - Chemical Society Reviews, 1991 - pubs.rsc.org
It is appropriate that the reaction vessels used for inert-atmospheric work, and in which many
modern organolithium preparations are carried out, honour the name of the pioneer of these …

The structural chemistry of organosilicon compounds

M Kaftory, M Kapon… - The chemistry of organic …, 1998 - Wiley Online Library
The question of how closely do the properties of organic compounds of silicon resemble
those of derivatives of its congener carbon atom was raised more than a century ago. A …

Silylphosphanes: Developments in phosphorus chemistry

G Fritz, P Scheer - Chemical Reviews, 2000 - ACS Publications
Silylphosphanes: Developments in Phosphorus Chemistry | Chemical Reviews ACS ACS
Publications C&EN CAS Find my institution Log In Chemical Reviews ACS Publications. Most …

Nature of the boron-phosphorus bond in monomeric phosphinoboranes and related compounds

DC Pestana, PP Power - Journal of the American Chemical …, 1991 - ACS Publications
Thenature of the bonding between boron and phosphorus in monomeric phosphinoboranes
(also called boryiphosphanes, ie, R2BPR2, R and R'= hydrocarbyl groups, B and P three …

Synthesis of the Bulky Phosphanide [P(SiiPr3)2] and Its Stabilization of Low-Coordinate Group 12 Complexes

OP Churchill, A Dase, LJ Taylor, SP Argent… - Inorganic …, 2024 - ACS Publications
Here, we report an improved synthesis of the bulky phosphanide anion [P (Si i Pr3) 2]− in
synthetically useful yields and its complexation to group 12 metals. The ligand is obtained as …

Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes,[cyclic]{[H2C (CH2) 3NLi] 3 …

DR Armstrong, D Barr, W Clegg… - Journal of the …, 1989 - ACS Publications
(CH2CH2NMe2) 2] and j [H2C (CH2) 3ÑLi] 2-TMEDA! 2 (2)[TMEDA= Me2N (CH2CH2)
NMe2], have been synthesized and characterized. X-ray diffraction has shown that both are …

Group I complexes of P-and as-donor ligands

K Izod - 2000 - Elsevier
Publisher Summary This chapter presents range of phosphorus (P)-and arsenic (As)-
containing ligands, with emphasis on those complexes in which there is an established …

Synthesis, properties, and reactivity of alkaline earth metal bis [bis (trialkylsilyl) amides]

M Westerhausen - Coordination chemistry reviews, 1998 - Elsevier
Due to their reactivity, the alkaline earth metal bis [bis (trimethylsilyl) amides] are valuable
synthons to incorporate the metal atoms in numerous molecules. The easy access of these …

Simple conversion of trisodium phosphide, Na 3 P, into silyl-and cyanophosphides and the structure of a terminal silver phosphide

G Le Corre, H Grützmacher - Dalton Transactions, 2022 - pubs.rsc.org
A reaction of trisodium phosphide (Na3P) with chlorosilanes allows for simple derivatization
into silyl-and cyano-substituted phosphanide species which were compared with each other …