Selective Electrocatalytic Conversion of Nitric Oxide to High Value‐Added Chemicals

D Wang, XF Lu, D Luan, XW Lou - Advanced Materials, 2024 - Wiley Online Library
The artificial disturbance in the nitrogen cycle has necessitated an urgent need for nitric
oxide (NO) removal. Electrochemical technologies for NO conversion have gained …

Carbonyl compounds′ journey to amide bond formation

T Narendar Reddy, A Beatriz… - Chemistry–An Asian …, 2019 - Wiley Online Library
The formation of amide bonds is one of the most stimulating emerging areas in organic and
medicinal chemistry. Amides are recognized as central building blocks in a plethora of …

Catalytic synthesis of amides via aldoximes rearrangement

P Crochet, V Cadierno - Chemical Communications, 2015 - pubs.rsc.org
Amide bond formation reactions are among the most important transformations in organic
chemistry because of the widespread occurrence of amides in pharmaceuticals, natural …

Direct and catalytic amide synthesis from ketones via transoximation and Beckmann rearrangement under mild conditions

K Hyodo, G Hasegawa, N Oishi… - The Journal of organic …, 2018 - ACS Publications
The Brønsted acid-catalyzed synthesis of secondary amides from ketones under mild
conditions is described via transoximation and Beckmann rearrangement using O-protected …

Radical Beckmann rearrangement and its application in the formal total synthesis of antimalarial natural product isocryptolepine via C–H activation

PS Mahajan, VT Humne, SD Tanpure… - Organic letters, 2016 - ACS Publications
The Beckmann rearrangement of ketoximes, mediated by ammonium persulfate-dimethyl
sulfoxide as a reagent, has been achieved under neutral conditions. Based on the radical …

Gut microbiota in healthy and unhealthy long-living people

S Zhang, B Zeng, Y Chen, M Yang, F Kong, L Wei, F Li… - Gene, 2021 - Elsevier
The human gut microbiota in long-living people has been characterized, however, its
metabolic potential is still largely unknown in this group. In this study, the gut microbiota was …

An overview of caprolactam synthesis

R Kumar, S Shah, P Paramita Das… - Catalysis …, 2019 - Taylor & Francis
Caprolactam is the precursor of many industrial chemical productions as in nylon industry,
plastic industry, paint industry, lysine synthesis and cross-linking for polyurethanes. The …

Recent approaches in tandem reactions catalyzed by MOF and MOF-based catalysts

M Shahiryar, S Kousar, MA Mudassir, M Irfan… - Journal of …, 2024 - Elsevier
Abstract Metal Organic Frameworks (MOF) are unique kind of materials which have highly
crystalline and porous nature. They have many active sites and with their tunable and tailor …

Tropylium‐BF4 as Organocatalyst for Microwave‐assisted Beckmann rearrangement in [TMG][BF4]: One‐pot conversion of Ketones to Amides

A Anchi, RG Kalkhambkar, SM Sutar, RS Naik… - …, 2023 - Wiley Online Library
The microwave assisted one pot efficient conversion of ketones into respective amides has
been achieved by utilization of environmentally benign catalytic system tailored by tropylium …

A one step synthesis ofcaprolactam out of cyclohexanone by combinded ammoximation and Beckmann rearrangement over Nb-MCM-41 catalysts

M Anilkumar, WF Hoelderich - Applied Catalysis B: Environmental, 2015 - Elsevier
Caprolactam was synthesized directly in one step out of cyclohexanone via combined liquid
phase ammoximation and Beckmann rearrangement using H 2 O 2 and NH 3 in presence of …