Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

One of the most common reactions of diazo compounds with alkenes is cyclopropanation,
which occurs through metal carbene or free carbene intermediates. Alternative …

Herein, we reported an N-heterocyclic carbene (NHC) and photo-co-catalyzed alkylacylation
of olefins in the presence of the versatile synthon diazo ester, providing a new idea for …

Direct difunctionalization of simple alkenes has been treated as a powerful synthetic strategy
for the construction of highly functionalized skeletons. In this study, direct oxidative coupling …

A visible-light-induced multicomponent reaction of ethyl diazoacetate, diarylamines, and
styrene-type alkenes is described. This novel 1, 2-difunctionalization of alkenes can be …

A mild visible light‐induced palladium‐catalyzed alkyl Heck reaction of diazo compounds
and N‐tosylhydrazones is reported. A broad range of vinyl arenes and heteroarenes with …

The oxidative coupling of photogenerated alkyl radicals with readily available styrenes is
disclosed. This visible-light-mediated method allows rapid access to a wide range of α-alkyl …

A copper/cobalt-catalyzed difunctionalization of alkenes with sulfonylazides and tert-butyl
hydroperoxide has been achieved. This protocol provides an efficient and direct …

Disclosed herein is an unprecedented cobalt-catalyzed trifluoromethylation–peroxidation of
unactivated alkenes. In this process the hydroperoxide acts as a radical initiator as well as a …