Paramagnetic chemical probes for studying biological macromolecules

Q Miao, C Nitsche, H Orton, M Overhand… - Chemical …, 2022 - ACS Publications
Paramagnetic chemical probes have been used in electron paramagnetic resonance (EPR)
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …

Nitroxide radical polymers for emerging plastic energy storage and organic electronics: fundamentals, materials, and applications

Y Xie, K Zhang, Y Yamauchi, K Oyaizu, Z Jia - Materials Horizons, 2021 - pubs.rsc.org
Increasing demand for portable and flexible electronic devices requires seamless
integration of the energy storage system with other electronic components. This ever …

Dye-sensitized photoelectrosynthesis cells for benzyl alcohol oxidation using a zinc porphyrin sensitizer and TEMPO catalyst

E Nikoloudakis, PB Pati, G Charalambidis… - ACS …, 2021 - ACS Publications
Exploring a catalytic reaction other than water oxidation at the photoanode of a
photoelectrochemical cell is probably a key feature to more efficiently generate the electrons …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Oriented internal electrostatic fields: an emerging design element in coordination chemistry and catalysis

AB Weberg, RP Murphy, NC Tomson - Chemical Science, 2022 - pubs.rsc.org
The power of oriented electrostatic fields (ESFs) to influence chemical bonding and reactivity
is a phenomenon of rapidly growing interest. The presence of strong ESFs has recently …

Stabilities, regeneration pathways, and electrocatalytic properties of nitroxyl radicals for the electrochemical oxidation of 5-hydroxymethylfurfural

AC Cardiel, BJ Taitt, KS Choi - ACS Sustainable Chemistry & …, 2019 - ACS Publications
2, 5-Furandicarboxylic acid (FDCA) is a near-market monomer that has been identified as a
viable biomass-derived replacement for petroleum-derived terephthalic acid in the synthesis …

The Transition from Metal-Based to Metal-Free Contrast Agents for T1 Magnetic Resonance Imaging Enhancement

OU Akakuru, MZ Iqbal, M Saeed, C Liu… - Bioconjugate …, 2019 - ACS Publications
Magnetic resonance imaging (MRI) has received significant attention as the noninvasive
diagnostic technique for complex diseases. Image-guided therapeutic strategy for diseases …

Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry

YB Vogel, L Zhang, N Darwish, VR Gonçales… - Nature …, 2017 - nature.com
Predicting or manipulating charge-transfer at semiconductor interfaces, from molecular
electronics to energy conversion, relies on knowledge generated from a kinetic analysis of …

Application of quantum chemical methods in polymer chemistry

F Ruiperez - International Reviews in Physical Chemistry, 2019 - Taylor & Francis
The rapid development of computational hardware and software, as well as the advances in
new theoretical methodologies have allowed quantum chemistry, in particular density …

Using internal electrostatic fields to manipulate the valence manifolds of copper complexes

AB Weberg, SP McCollom, LM Thierer, MR Gau… - Chemical …, 2021 - pubs.rsc.org
A series of tetradentate tris (phosphinimine) ligands (R3P3tren) was developed and bound
to CuI to form the trigonal pyramidal, C3v-symmetric cuprous complexes [R3P3tren …