Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

The generation and intermolecular functionalisation of carbon-centred radicals has broad
potential synthetic utility. Herein, we show that benzylic radicals may be generated …

A two-step synthesis sequence furnishes quadruply annulated borepins in high yields. The
first step involves a nucleophilic substitution reaction between aryl–BF3K salts (aryl= mesityl …

Stereoselective reactions at the anomeric carbon constitute the cornerstone of preparative
carbohydrate chemistry. Here, we report stereoselective C-arylation and etherification …

Organoboron compounds have a wide-range of applications in synthetic methodologies,
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …

Tetrapyrrole macrocycles are central to photosynthesis yet a single macrocycle does not
carry out photosynthesis; rather, assemblies of tetrapyrrole macrocycles work in concert in …

While the organotrifluoroborate group is commonly used as a leaving group in cross-
coupling reactions, we now show that their high stability can be used to protect the Lewis …

Herein, we demonstrate the use of α‐boryl aldehydes and acyl boronates in the synthesis of
aminoboronic acid derivatives. This work highlights the untapped potential of boron …

Both α-and β-aminoboronic acids and their derivatives are particularly useful as synthetic
precursors, biochemical probes and drugs, although the development of novel compounds …