Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Rare-earth ions are characterized by large unquenched orbital angular momentum
associated with the internal nature of the valence f orbitals. In fact, with the exception of …

Rare-earth β-diketonates are complexes of β-diketones (1, 3-diketones) with rare-earth ions.
These complexes are the most popular and the most intensively investigated rare-earth …

Numerous molecular compounds in which a paramagnetic Ln (III) ion is in interaction with a
second spin carrier such as a transition metal ion or an organic radical have been …

In the past two decades or so, a large number of heteropoly-metallic compounds have been
described. The studies of these compounds have often been performed either in relation to …

METAL NITRONYL NITROXIDE COMPLEXES 333 first can be the understanding of the
fundamental bonding interactions between the unpaired electrons of the radicals with the …

This important book is devoted to covering the synthetic aspects of nitroxide chemistry. The
problems of application and physicochemical properties of nitroxides are considered in the …

Three yearsago, we initiated a new project concerning rare earth metal molecular
chemistry.* 1 11· 2 The reasons for that were as follows,(i) From a synthetic point of view, the …

Abstract One-dimensional (1D) magnetic systems have been extensively studied over the
last few decades because they are more chemically tractable between zero-dimensional …

A ferromagnetically coupled gadolinium–radical compound is described. A series of three
lanthanide complexes of general formula [Ln (organic radical) 2 (NO3) 3](Ln= Y3+, La3+ …