Recent findings and future directions in photosynthetic hydrogen evolution using polypyridine cobalt complexes

F Droghetti, F Lucarini, A Molinari, A Ruggi… - Dalton …, 2022 - pubs.rsc.org
The production of hydrogen gas using water as the molecular substrate currently represents
one of the most challenging and appealing reaction schemes in the field of artificial …

Bioinspired motifs in proton and CO 2 reduction with 3d-metal polypyridine complexes

F Droghetti, A Amati, A Ruggi, M Natali - Chemical Communications, 2024 - pubs.rsc.org
The synthesis of active and efficient catalysts for solar fuel generation is nowadays of high
relevance for the scientific community, but at the same time poses great challenges. Critical …

Covalent Attachment of Cobalt Bis (Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable …

VA Larson, N Lehnert - ACS Catalysis, 2023 - ACS Publications
Hydrogen (H2) can be produced in the water splitting reaction, specifically on the cathodic
side through the hydrogen evolution reaction (HER), where two protons and two electrons …

Combining Imine Condensation Chemistry with [3, 3] Diaza‐Cope Rearrangement for One‐Step Formation of Hydrolytically Stable Chiral Architectures

F Begato, R Penasa, K Wurst, G Licini… - Angewandte …, 2023 - Wiley Online Library
Dynamic covalent chemistry (DCC) has, in recent years, provided valuable tools to
synthesize molecular architectures of increasing complexity. We have also taken advantage …

Decrypting the hydrogen evolution in alkaline water with novel magnetoactive cobalt (II) complex-driven cobalt oxide electrocatalysts

S Saha, N Diyali, S Diyali, SJ Panda, M Das… - Dalton …, 2024 - pubs.rsc.org
Under the gravity of future socio-economic development, the viability of water electrolysis
still hinges on the accessibility of stable earth-abundant electrocatalysts and net energy …

Strong Enhancement in Cobalt (II)‐TPMA Aqueous Hydrogen Photosynthesis through Intramolecular Proton Relay

F Droghetti, F Begato, M Raulin, G Musiu… - Angewandte …, 2024 - Wiley Online Library
Photosynthetic hydrogen generation by cobalt (II) tris (2‐pyridylmethyl) amine (TPMA)
complexes is mainly limited by protonation kinetics and decomposition routes involving …

Non-synergistic photocatalysis of CO2-to-CO conversion by a binuclear complex of rigidly linking two cobalt catalytic centers

W Xia, YY Ren, J Liu, BY Deng, F Wang - Journal of Photochemistry and …, 2022 - Elsevier
A novel binuclear cobalt complex C1 of rigidly linking two [Co (TPA) Cl] Cl moieties at meta
positions of a benzene was synthesized and characterized as a catalyst for homogeneous …

Selective and Efficient Light-Driven CO2 Reduction to CO with a Heptacoordinated Polypyridine Iron(II) Catalyst

F Droghetti, F Lemken, L Rulíšek, A Ruggi… - ACS …, 2024 - ACS Publications
The selective generation of carbon-based products in the presence of proton donors
currently represents one of the major goals in the catalysis of the CO2 reduction reaction …

α-Fe2O3/, Co3O4/, and CoFe2O4/MWCNTs/Ionic Liquid Nanocomposites as High-Performance Electrocatalysts for the Electrocatalytic Hydrogen Evolution …

J Ibarra, MJ Aguirre, R Del Río, R Henriquez… - International Journal of …, 2024 - mdpi.com
Transition metal oxides are a great alternative to less expensive hydrogen evolution reaction
(HER) catalysts. However, the lack of conductivity of these materials requires a conductor …

TMPA‐based Cavitary Cobalt (II) Funnel Complexes

N Nyssen, A Abudayyeh, F Zhurkin… - European Journal of …, 2024 - Wiley Online Library
The synthesis of a series of mononuclear, dicationic CoII funnel complexes is reported
herein. Three ligands Calix‐TMPAX present a calix [6] arene cone closed at its small rim by …