Methods for preparation of hexagonal boron nitride nanomaterials

D Yang, P Dai, X Jiang, SM Alshehri… - Chemistry of …, 2024 - ACS Publications
Hexagonal boron nitride (h-BN) represents a promising inorganic compound, garnering
widespread attention for its unique combination of electrical insulation, thermal conductivity …

Exceptionally long covalent CC bonds—A local vibrational mode study

AAA Delgado, A Humason, R Kalescky, M Freindorf… - Molecules, 2021 - mdpi.com
For decades one has strived to synthesize a compound with the longest covalent C− C bond
applying predominantly steric hindrance and/or strain to achieve this goal. On the other …

An amine–borane system featuring room‐temperature dehydrogenation and regeneration

G Zhang, D Morrison, G Bao, H Yu… - Angewandte …, 2021 - Wiley Online Library
Amine–borane complexes have been extensively studied as hydrogen storage materials.
Herein, we report a new amine–borane system featuring a reversible dehydrogenation and …

The Existence of a N→C Dative Bond in the C60–Piperidine Complex

M Lamanec, R Lo, D Nachtigallová… - Angewandte …, 2021 - Wiley Online Library
The complexes formed between carbon allotropes (C20, C60 fullerenes, graphene, and
single‐wall carbon nanotubes) and piperidine have been investigated by means of …

From Pyridine Adduct of Borabenzene to (In) Finite Graphene Architectures Functionalized with N→ B Dative Bonds. Prototype Systems of Strong One-and Two …

P Karamanis, N Otero, D Xenides… - The Journal of …, 2020 - ACS Publications
The synthesis and optoelectronics properties of polyaromatic hydrocarbons (PAHs) doped
with boron and nitrogen units (BN) monopolize the interest of increasing numbers of …

Mono‐and Di‐Mesoionic Carbene‐Boranes: Synthesis, Structures and Utility as Reducing Agents

F Stein, M Kirsch, J Beerhues, U Albold… - European Journal of …, 2021 - Wiley Online Library
Mesoionic carbenes (MIC) of the 1, 2, 3‐triazol‐5‐ylidene type are currently popular ligands
in organometallic chemistry. Their use in main group chemistry has been rather limited. In …

N/O→ B dative bonds supplemented by N–HN/HC hydrogen bonds make BN-cages an attractive candidate for DNA-nucleobase adsorption–an MP2 prediction

S Muniyandi, R Sundaram, AK Roy… - Physical Chemistry …, 2022 - pubs.rsc.org
The response of B12N12-nanocages towards DNA-nucleobases (adenine, guanine,
cytosine, and thymine) is investigated using MP2 and DFT (M06-2X) levels of theory with the …

Diboramacrocycles: reversible borole dimerisation–dissociation systems

S Fuchs, A Jayaraman, I Krummenacher, L Haley… - Chemical …, 2022 - pubs.rsc.org
We report that the outcome of the tin–boron exchange reaction of a mixed thiophene-benzo-
fused stannole with aryldibromoboranes is associated with the steric bulk of the aryl …

Solvent Effect on Dative and Ionic Bond Strengths: A Unified Theory from Potential Analysis and Valence‐Bond Computations

X Peng, J Li, Y Fan, X Wang, S Yin… - … –A European Journal, 2024 - Wiley Online Library
Solvent molecules interact with a solute through various intermolecular forces. Here we
employed a potential energy surface (PES) analysis to interpret the solvent‐induced …

Development of an unsymmetrical cyclopropenimine‐guanidine platform for accessing strongly basic proton sponges and boron‐difluoride diaminonaphthalene …

M Guest, R Le Sueur, M Pilkington… - … –A European Journal, 2020 - Wiley Online Library
An unsymmetrical guanidine‐cyclopropenimine proton sponge DAGUN and the related BF2‐
chelate DAGBO are reported. Insight into the structural, electronic, bonding and …