Theoretical expression of the average activation− deactivation equilibrium constant in controlled/living free-radical copolymerization operating via reversible …

B Charleux, J Nicolas, O Guerret - Macromolecules, 2005 - ACS Publications
The average activation− deactivation equilibrium constant,〈 K∟, was determined on a
theoretical basis for controlled free-radical copolymerizations operating via a reversible …

A large-strain and ultrahigh energy density dielectric elastomer for fast moving soft robot

W Feng, L Sun, Z Jin, L Chen, Y Liu, H Xu… - Nature …, 2024 - nature.com
Dielectric elastomer actuators (DEAs) with large actuation strain and high energy density are
highly desirable for actuating soft robots. However, DEAs usually require high driving …

Covalently Grafted Graphene Oxide/Poly(Cn-acrylate) Nanocomposites by Surface-Initiated ATRP: An Efficient Antifriction, Antiwear, and Pour-Point-Depressant …

A Kumar, B Behera, GD Thakre… - Industrial & Engineering …, 2016 - ACS Publications
Nanocomposites of graphene oxide with polyacrylates with varying numbers of carbon
atoms from 10 to 18 were prepared by surface-initiated atom-transfer radical polymerization …

Atom transfer radical copolymerization of glycidyl methacrylate and methyl methacrylate

D Neugebauer, K Bury, M Wlazło - Journal of applied polymer …, 2012 - Wiley Online Library
Glycidyl methacrylate (GMA) and methyl methacrylate (MMA) copolymers were synthesized
by atom transfer radical polymerization (ATRP). The effect of different molar fractions of …

Nitroxide‐mediated free‐radical copolymerization of styrene with butyl acrylate

R Cuervo‐Rodriguez, V Bordegé… - Journal of Polymer …, 2004 - Wiley Online Library
Controlled free‐radical copolymerization of styrene (S) and butyl acrylate (BA) was achieved
by using a second‐generation nitroxide, N‐tert‐butyl‐N‐[1‐diethylphosphono‐(2, 2 …

Isobutylene‐rich macromonomers: Dynamics and yields of peroxide‐initiated crosslinking

JM Dakin, KVS Shanmugam, C Twigg… - Journal of Polymer …, 2015 - Wiley Online Library
New isobutylene‐rich elastomers bearing multiple pendant styrenic, acrylic, maleimidic,
vinylic, and allylic functional groups have been prepared and examined in the context of …

Resonance, polar, and steric effects of substituent on monomer reactivity in radical polymerization of alkyl 4‐vinylbenzoate and butylacrylate

HS Bisht, SS Ray, AK Chatterjee - Journal of Polymer Science …, 2003 - Wiley Online Library
In ionic polymerization the reactivity of the monomer depends not only on its structure but
also on the nature of the catalyst and solvent used; therefore, it is difficult to find a …

Polystyrene‐block‐poly(methyl methacrylate): Initiation Issues with Block Copolymer Formation Using ARGET ATRP

TJ Aitchison, M Ginic‐Markovic, S Clarke… - Macromolecular …, 2012 - Wiley Online Library
The synthesis, kinetics, and characterization of polystyrene and poly (methyl methacrylate)
block copolymers produced by ARGET ATRP are discussed. Halogen exchange is used and …

Expanded corn starch a novel material as macroinitiator/solid support in SI and AGET ATRP: GMA polymerization

A Bansal, SS Ray, AK Chatterjee - Journal of Polymer Research, 2015 - Springer
Here we have shown the use of expanded corn starch (ECS) as an effective macro-initiator
in Surface Initiated Atom Transfer Radical Polymerization (SI-ATRP) as well as a solid …

Polypropylene thermosets by VBTEMPO-mediated radical crosslinking

KE Ozols, BM Molloy, JS Parent - Polymer, 2017 - Elsevier
New chemistry for preparing polypropylene (PP) thermosets is described, wherein radical
degradation suffered during conventional peroxide treatment is overcome using a nitroxyl …