Investigations of reactive intermediates that possess high energies and unusual reactivities
comprise one of the most fascinating topics of today's chemistry. Such studies push the limits …

This review provides an overview of density functional theory (DFT) calculations in a
consequence with spectroelectrochemical measurements on mononuclear and …

Abstract Electrochromic/electrofluorescence (EC/EFC) bifunctional polymer materials with
electrochemically switchable colors and fluorescence intensities have attracted significant …

Five new, constrained, aryl-substituted 4, 4-difluoro-4-bora-3a, 4a-diaza-s-indacene
(BODIPY) dyes (3f, g and 4h− j) were prepared and investigated to see if they have more …

Hopping and superexchange are generally considered to be alternative electron-transfer
mechanisms in molecular systems. In this work we used mixed-valence radical cations as …

Electronic and steric effects are known to greatly influence the structure, characteristics and
reactivity of organic compounds. A typical π bond is weakened by oxidation (corresponding …

A formal gold‐for‐chromium transmetalation allowed the gold carbenoid species
[Cy3PAuCAr2] NTf2 (11)(Ar= pMeOC6H4‐) to be obtained in crystalline form. The structure …

Radical cations and dications of π-conjugated oligomers and polymers, such as poly (para-
phenylene) s, poly (para-phenylenevinylene) s, and poly (thiophene) s, play a pivotal role as …

The design and synthesis of broad absorption electrochromic materials (ECMs) that
modulate visible and near infrared light are important for energy-saving smart windows …

The formation of odd-electron bonds [1] in first-row maingroup derivatives is a relatively rare
phenomenon.[2, 3] The rarity of such linkages can be correlated to the intrinsic instability of …