Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

The selective oxidation of C H bonds and the use of O2 as a stoichiometric oxidant
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …

Organometallic CuIII species have been invoked in many copper-catalyzed reactions, but
until recently, experimental evidences were lacking. The advent of new spectroscopic …

Copper (II)-mediated C–H oxidation is the subject of extensive interest in synthetic
chemistry, but the mechanisms of many of these reactions are poorly understood. Here, we …

Over the past decade, numerous reports have focused on the development and applications
of Cu-mediated C–H functionalization reactions; however, to date, little is known about the …

The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …

Following immediately after the serendipitous discovery of N-confused porphyrins,
remarkably diverse carbaporphyrinoid systems have been synthesized and investigated. By …

Die selektive Oxidation von C‐H‐Bindungen und der Einsatz von O2 als stöchiometrisches
Oxidationsmittel stellen zwei wesentliche Herausforderungen in der organischen Chemie …

Copper (II) pyridyliminoarylsulfonate complexes with chloride or triflate counteranions were
employed in Chan–Evans–Lam (CEL) couplings of N-nucleophiles and arylboronic acids …

This article introduces an overview of progressively developing chemistry of N-confused
porphyrin and related macrocycles. Study on confusion results in discovery of fusion and …