Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes

VWW Yam, VKM Au, SYL Leung - Chemical reviews, 2015 - ACS Publications
The spontaneous self-organization of matters has always been one of the most fascinating
wonders in the world. Self-assembly refers to “the autonomous organization of components …

Origin of the photoluminescence of metal nanoclusters: from metal-centered emission to ligand-centered emission

TQ Yang, B Peng, BQ Shan, YX Zong, JG Jiang, P Wu… - Nanomaterials, 2020 - mdpi.com
Recently, metal nanoclusters (MNCs) emerged as a new class of luminescent materials and
have attracted tremendous interest in the area of luminescence-related applications due to …

Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission

T Jia, ZJ Guan, C Zhang, XZ Zhu, YX Chen… - Journal of the …, 2023 - ACS Publications
Owing to the inherent instability caused by the low Cu (I)/Cu (0) half-cell reduction potential,
Cu (0)-containing copper nanoclusters are quite uncommon in comparison to their Ag and …

Intramolecular charge transfer enables highly-efficient X-ray luminescence in cluster scintillators

N Zhang, L Qu, S Dai, G Xie, C Han, J Zhang… - Nature …, 2023 - nature.com
Luminescence clusters composed of organic ligands and metals have gained significant
interests as scintillators owing to their great potential in high X-ray absorption, customizable …

Highly Effective Hybrid Copper (I) Iodide Cluster Emitter with Negative Thermal Quenched Phosphorescence for X‐Ray Imaging

Q Hu, C Zhang, X Wu, G Liang, L Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
The low efficiency triplet emission of hybrid copper (I) iodide clusters is a critical obstacle to
their further practical optoelectronic application. Herein, we present an efficient hybrid …

Mechanoresponsive luminescent molecular assemblies: an emerging class of materials

Y Sagara, S Yamane, M Mitani, C Weder… - Advanced …, 2016 - Wiley Online Library
The possibility to change the molecular assembled structures of organic and organometallic
materials through mechanical stimulation is emerging as a general and powerful concept for …

Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior

J Wu, Y Guo, JL Qi, WD Yao, SX Yu, W Liu… - Angewandte …, 2023 - Wiley Online Library
Although phase transition materials (PTMs) under external stimuli are of great research
interest duo to their rich potential applications, it is still challenging to explore multi …

Hybrid thermally activated nanocluster fluorophores for X-ray scintillators

P Yuan, T He, Y Zhou, J Yin, H Zhang, Y Zhang… - ACS Energy …, 2023 - ACS Publications
Thermally activated delayed fluorescence (TADF) X-ray scintillators have attracted
increasing attention because of their theoretical ability to utilize 100% radiation-induced …

White-light-emitting lanthanide metallogels with tunable luminescence and reversible stimuli-responsive properties

P Chen, Q Li, S Grindy… - Journal of the American …, 2015 - ACS Publications
We have developed model light-emitting metallogels functionalized with lanthanide metal–
ligand coordination complexes via a terpyridyl-end-capped four-arm poly (ethylene glycol) …

Assembly-induced enhancement of Cu nanoclusters luminescence with mechanochromic property

Z Wu, J Liu, Y Gao, H Liu, T Li, H Zou… - Journal of the …, 2015 - ACS Publications
Metal nanoclusters (NCs) as a new class of phosphors have attracted a great deal of interest
owing to their unique electronic structure and subsequently molecule-like optical properties …