The effects of alkylthio chains on the properties of symmetric liquid crystal dimers

E Cruickshank, GJ Strachan, MM Majewska… - New Journal of …, 2023 - pubs.rsc.org
The synthesis and characterisation of four series of symmetric liquid crystal dimers
containing either alkylthio or alkyloxy terminal chains are reported. The (E, E)-[pentane-1, 5 …

Scalable electrochemical reduction of sulfoxides to sulfides

Z Kong, C Pan, M Li, L Wen, W Guo - Green Chemistry, 2021 - pubs.rsc.org
A scalable reduction of sulfoxides to sulfides in a sustainable way remains an unmet
challenge. This report discloses an electrochemical reduction of sulfoxides on a large scale …

Phosphorus-alloying as a powerful method for designing highly active and durable metal nanoparticle catalysts for the deoxygenation of sulfoxides: ligand and …

H Ishikawa, S Yamaguchi, A Nakata, K Nakajima… - JACS Au, 2022 - ACS Publications
The modification of metal nanoparticles (NPs) by incorporating additional metals is a key
technique for developing novel catalysts. However, the effects of incorporating nonmetals …

S-Protected Cysteine Sulfoxide-Enabled Tryptophan-Selective Modification with Application to Peptide Lipidation

D Kobayashi, E Kuraoka, J Hayashi… - ACS Medicinal …, 2022 - ACS Publications
Lipidation of peptides is a promising means of modification that can improve the therapeutic
character of biologically active peptides. Here, a novel lipidation protocol for peptides is …

Visible light induced deoxygenation of sulfoxides with isopropanol

J Zhao, Z Luo, Y Liu, S Chen, J He, J Xu… - Organic Chemistry …, 2023 - pubs.rsc.org
We report visible light induced deoxygenation of sulfoxides to sulfides catalyzed by
anthraquinone under irradiation at 430–440 nm at room temperature employing cheap …

Site-Selective Synthesis of Aryl Sulfides via Oxidative Aromatization of Cyclohexanones with Thiophenols

F Xiao, M Tang, H Huang, GJ Deng - The Journal of Organic …, 2021 - ACS Publications
We have introduced a metal-free facile access for the thiolation/aromatization of
cyclohexanones with thiophenols to the corresponding aryl sulfides. The dehydroaromatic …

Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading

FF Xu, ZL Ruan, PQ Huang - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Herein, we report the catalytic deoxygenative reduction of sulfoxides to sulfides in good to
excellent yields. This method was enabled by the combination of Vaska's complex with poly …

Triethyl amine as an effective reducing agent for sulfoxide deoxygenation

X Gao, F Chen, MY Jin, C Xu - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
Enabled by triethyl amine (Et3N) and thionyl chloride (SOCl2), an efficient and practical
protocol for deoxygenation of sulfoxide to sulfide was developed. This new method features …

Iodonium Salt‐Mediated Oxidation of Sulfides to Sulfoxides by DMSO

E Avramidou, AK Triandafyllou… - European Journal of …, 2024 - Wiley Online Library
Compounds bearing the sulfoxide moiety display an important class of molecules in
pharmaceutical industry. Many efforts have been made towards the development of novel …

Regioselective Organocatalyzed Monochlorination of Arenes with Electrophilic Chlorosulfoniums

A Garay‐Talero, P Acosta‐Guzmán… - Advanced Synthesis …, 2023 - Wiley Online Library
This manuscript presents a regioselective chlorination of arenes, yielding almost exclusively
the monochlorinated product. It tolerates free hydroxy groups, 1°, 2° and 3° amines, and …