Rethinking the role of excess/residual lead iodide in perovskite solar cells

Y Gao, H Raza, Z Zhang, W Chen… - Advanced Functional …, 2023 - Wiley Online Library
It is widely believed that excess/residual lead iodide (PbI2) can affect the performance of
perovskite solar cells. Moderate PbI2 can enhance efficiency by passivating defects, while …

In Situ and Operando Characterizations of Metal Halide Perovskite and Solar Cells: Insights from Lab-Sized Devices to Upscaling Processes

R Szostak, A de Souza Gonçalves… - Chemical …, 2023 - ACS Publications
The performance and stability of metal halide perovskite solar cells strongly depend on
precursor materials and deposition methods adopted during the perovskite layer …

Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells

N Aristidou, C Eames, I Sanchez-Molina, X Bu… - Nature …, 2017 - nature.com
Methylammonium lead halide perovskites are attracting intense interest as promising
materials for next-generation solar cells, but serious issues related to long-term stability …

Temperature-Dependent Optical Band Gap in CsPbBr3, MAPbBr3, and FAPbBr3 Single Crystals

G Mannino, I Deretzis, E Smecca… - The journal of …, 2020 - ACS Publications
Single crystals represent a benchmark for understanding the bulk properties of halide
perovskites. We have indeed studied the dielectric function of lead bromide perovskite …

Cesium lead halide perovskites with improved stability for tandem solar cells

RE Beal, DJ Slotcavage, T Leijtens… - The journal of …, 2016 - ACS Publications
A semiconductor that can be processed on a large scale with a bandgap around 1.8 eV
could enable the manufacture of highly efficient low cost double-junction solar cells on …

Impact of H 2 O on organic–inorganic hybrid perovskite solar cells

J Huang, S Tan, PD Lund, H Zhou - Energy & Environmental Science, 2017 - pubs.rsc.org
The performance and stability of organic–inorganic hybrid perovskite solar cells (PSCs) is
sensitive to water and moisture in an ambient environment. Understanding how H2O …

Defect Tolerance to Intolerance in the Vacancy-Ordered Double Perovskite Semiconductors Cs2SnI6 and Cs2TeI6

AE Maughan, AM Ganose, MM Bordelon… - Journal of the …, 2016 - ACS Publications
Vacancy-ordered double perovskites of the general formula A 2 BX 6 are a family of
perovskite derivatives composed of a face-centered lattice of nearly isolated [BX 6] units with …

Towards enabling stable lead halide perovskite solar cells; interplay between structural, environmental, and thermal stability

T Leijtens, K Bush, R Cheacharoen, R Beal… - Journal of Materials …, 2017 - pubs.rsc.org
Metal halide perovskite solar cells are rapidly becoming increasingly competitive with
conventional PV technologies. While their efficiencies have been often touted as …

Is Excess PbI2 Beneficial for Perovskite Solar Cell Performance?

F Liu, Q Dong, MK Wong, AB Djurišić… - Advanced Energy …, 2016 - Wiley Online Library
Unreacted lead iodide is commonly believed to be beneficial to the efficiency of
methylammonium lead iodide perovskite based solar cells, since it has been proposed to …

Optical Transitions in Hybrid Perovskite Solar Cells: Ellipsometry, Density Functional Theory, and Quantum Efficiency Analyses for

M Shirayama, H Kadowaki, T Miyadera, T Sugita… - Physical Review …, 2016 - APS
Light-induced photocarrier generation is an essential process in all solar cells, including
organic-inorganic hybrid (CH 3 NH 3 PbI 3) solar cells, which exhibit a high short-circuit …