Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

N-aryl and N-alkyl substituted pyridine-2, 6-diimines (pdi) are useful tridentate ligands that
are redox-active and can coordinate to main group elements, transition metal ions …

The electrocatalytic activity for CO2 reduction is greatly enhanced for Co complexes with
pyridyldiimine-based ligands through the stepwise integration of three synergistic …

Hydride transfer (HT) is a fundamental step in a wide range of reaction pathways, including
those mediated by dihydropyridinates (DHP− s). Coordination of ions directly to the pyridine …

We report the synthesis of cationic 2, 6-bisiminopyridine organoaluminum complexes,[(BIP)
AlR2]+, as stable BArF4–or PF6–salts, and their reversible single-electron reduction into …

A cobalt complex bearing a κ‐N3P2 ligand is presented (1+ or CoI (L), where L is (1E, 1′ E)‐
1, 1′‐(pyridine‐2, 6‐diyl) bis (N‐(3‐(diphenylphosphanyl) propyl) ethan‐1‐imine) …

Water-stable organic mixed valence (MV) compounds have been prepared by the reaction
of reduced bis (imino) pyridine ligands (I2P) with the trichloride salts of Al, Ga, and In. The …

Molecular design ultimately furnishes improvements in performance over time, and this has
been the case for Rh‐and Ir‐based molecular catalysts currently used in transfer …

Diiminophenyl (dimph) proved to be an excellent ligand platform to stabilise a low-valent
phosphorus centre. The resultant compound dimphP (3), which can be rationalized as an …

Applications of aluminum as a catalyst for organic/inorganic transformation reactions are
ideal because of its easy availability, inexpensiveness, and non-toxicity. However …