Halogen bonding and chalcogen bonding mediated sensing

R Hein, PD Beer - Chemical Science, 2022 - pubs.rsc.org
Sigma–hole interactions, in particular halogen bonding (XB) and chalcogen bonding (ChB),
have become indispensable tools in supramolecular chemistry, with wide-ranging …

Active template synthesis

R Jamagne, MJ Power, ZH Zhang, G Zango… - Chemical Society …, 2024 - pubs.rsc.org
The active template synthesis of mechanically interlocked molecular architectures exploits
the dual ability of various structural elements (metals or, in the case of metal-free active …

Redox-switchable chalcogen bonding for anion recognition and sensing

R Hein, A Docker, JJ Davis… - Journal of the American …, 2022 - ACS Publications
Inspired by the success of its related sigma-hole congener halogen bonding (XB),
chalcogen bonding (ChB) is emerging as a powerful noncovalent interaction with a plethora …

Exploiting the Catenane Mechanical Bond Effect for Selective Halide Anion Transmembrane Transport

H Min Tay, TG Johnson, A Docker… - Angewandte Chemie …, 2023 - Wiley Online Library
The first examples of [2] catenanes capable of selective anion transport across a lipid bilayer
are reported. The neutral halogen bonding (XB)[2] catenanes were prepared via a chloride …

Unravelling the potential of sigma hole-assisted co-crystallization: Highlighting recent developments

R Siddiqui, J Rani, HM Titi, R Patra - Coordination Chemistry Reviews, 2024 - Elsevier
In the past several decades, the field of cocrystal engineering has developed into a vital
research topic in supramolecular chemistry, holding the foremost scope in crystal …

Exploiting the mechanical bond effect for enhanced molecular recognition and sensing

JT Wilmore, PD Beer - Advanced Materials, 2024 - Wiley Online Library
The ubiquity of charged species in biological and industrial processes has resulted in ever‐
increasing interest in their selective recognition, detection, and environmental remediation …

Fine‐Tuning Substrate–Catalyst Halogen–Halogen Interactions for Boosting Enantioselectivity in Halogen‐Bonding Catalysis

AC Keuper, K Fengler, F Ostler… - Angewandte Chemie …, 2023 - Wiley Online Library
A new approach towards highly enantioselective halogen‐bonding catalysis has been
developed. To circumvent the intrinsic issues of the nature of the halogen‐bond (XB) and the …

Halogen‐Bonding Heteroditopic [2] Catenanes for Recognition of Alkali Metal/Halide Ion Pairs

HM Tay, YC Tse, A Docker, C Gateley… - Angewandte …, 2023 - Wiley Online Library
The first examples of halogen bonding (XB) heteroditopic homo [2] catenanes were
prepared by discrete Na+ template‐directed assembly of oligo (ethylene glycol) units …

Mechanically interlocked host systems for ion-pair recognition

A Arun, HM Tay, PD Beer - Chemical Communications, 2024 - pubs.rsc.org
The ever-increasing interest directed towards the construction of host architectures capable
of the strong and selective recognition of various ionic species of biological, medical and …

Halogen bonding BODIPY-appended pillar [5] arene for the optical sensing of dicarboxylates and a chemical warfare agent simulant

AJ Taylor, JT Wilmore, PD Beer - Chemical Communications, 2024 - pubs.rsc.org
A pillar [5] arene host, functionalised with halogen bonding (XB) recognition sites and
BODIPY fluorophores, demonstrates strong binding and optical sensing of environmentally …