The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …

One of the most challenging tasks in organic synthesis is to control selectivities, especially
switching the well-known selectivity to obtain new isomers that were previously inaccessible …

While palladium catalysis is ubiquitous in modern chemical research, the recovery of the
active transition‐metal complex under routine laboratory applications is frequently …

An electron rich Ni (I)–Ni (I) bond supported by a doubly reduced naphthyridine–diimine
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …

Building on our recent disclosure of catalysis at dinuclear PdI sites, we herein report the
application of this concept to the realization of the first catalytic method to convert aryl …

This report widens the repertoire of emerging PdI catalysis to carbon–heteroatom, that is, C−
S bond formation. While Pd0‐catalyzed protocols may suffer from the formation of poisonous …

The application of environmentally benign, cheap, and economically viable oxidation
procedures is a key challenge of homogeneous, oxidative alkane functionalization. The …

Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known,
those that release> 2 equiv of H2 are uncommon. Herein, we report the synthesis of Mo …

Two formal palladium carbene complexes,[PC (sp2) P] Pd (PR3)(3: R= Me; 4: R= Ph) were
isolated and characterized from [PC (sp3) H2P]([PC (sp3) H2P]= bis [2-(di …

The rotational spectrum of thiophene (cC 4 H 4 S) has been collected between 8 and 360
GHz. Samples of varying deuterium-enrichment were synthesized to yield all possible …