Synergy of 3D and 2D perovskites for durable, efficient solar cells and beyond

I Metcalf, S Sidhik, H Zhang, A Agrawal… - Chemical …, 2023 - ACS Publications
Three-dimensional (3D) organic–inorganic lead halide perovskites have emerged in the
past few years as a promising material for low-cost, high-efficiency optoelectronic devices …

The 2D halide perovskite rulebook: how the spacer influences everything from the structure to optoelectronic device efficiency

X Li, JM Hoffman, MG Kanatzidis - Chemical reviews, 2021 - ACS Publications
Two-dimensional (2D) halide perovskites have emerged as outstanding semiconducting
materials thanks to their superior stability and structural diversity. However, the ever-growing …

Amidino-based Dion-Jacobson 2D perovskite for efficient and stable 2D/3D heterostructure perovskite solar cells

T Yang, C Ma, W Cai, S Wang, Y Wu, J Feng, N Wu… - Joule, 2023 - cell.com
In metal halide perovskite solar cells the formation of a 2D/3D bulk heterostructure has a
positive effect on device stability but can be detrimental to charge transport and power …

Electron‐phonon coupling suppression by enhanced lattice rigidity in 2D perovskite single crystals for high‐performance X‐Ray detection

B Zhang, T Zheng, J You, C Ma, Y Liu… - Advanced …, 2023 - Wiley Online Library
Abstract 2D Dion− Jacobson (DJ) perovskite single crystals (PSCs) usually demonstrate
better X‐ray detection performance than Ruddlesden‐Popper (RP) PSCs. However, the …

Charge‐carrier transport in quasi‐2D Ruddlesden–Popper perovskite solar cells

L Yan, J Ma, P Li, S Zang, L Han, Y Zhang… - Advanced …, 2022 - Wiley Online Library
In recent years, 2D Ruddlesden–Popper (2DRP) perovskite materials have been explored
as emerging semiconductor materials in solar cells owing to their excellent stability and …

Tuning Structure and Excitonic Properties of 2D Ruddlesden–Popper Germanium, Tin, and Lead Iodide Perovskites via Interplay between Cations

W Mihalyi-Koch, G Folpini, CR Roy… - Journal of the …, 2023 - ACS Publications
The compositional tunability of 2D metal halide perovskites enables exploration of diverse
semiconducting materials with different structural features. However, rationally tuning the 2D …

Understanding Electron–Phonon Interactions in 3D Lead Halide Perovskites from the Stereochemical Expression of 6s2 Lone Pairs

X Huang, X Li, Y Tao, S Guo, J Gu… - Journal of the …, 2022 - ACS Publications
The electron–phonon (e–ph) interaction in lead halide perovskites (LHPs) plays a role in a
variety of physical phenomena. Unveiling how the local lattice distortion responds to charge …

Stereochemical expression of ns2 electron pairs in metal halide perovskites

Y Fu, S Jin, XY Zhu - Nature Reviews Chemistry, 2021 - nature.com
Metal halide perovskites (MHPs) are characterized as strongly anharmonic and dynamic
lattices. While there is a consensus on the solvation-like polarization effect in these …

Pressure-regulated excitonic transitions in emergent metal halides

Q Li, B Xu, Z Quan - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Emergent metal halides are generating significant interest as novel optical
materials, and their diverse applications have brought them to the spotlight of chemistry and …

Stereochemically active lone pairs and nonlinear optical properties of two-dimensional multilayered tin and germanium iodide perovskites

X Li, Y Guan, X Li, Y Fu - Journal of the American Chemical …, 2022 - ACS Publications
Two-dimensional (2D) metal halide perovskites are promising tunable semiconductors.
Previous studies have focused on Pb-based structures, whereas the multilayered Sn-and Ge …