Cyclotriphosphazene based materials: Structure, functionalization and applications

D Wang, X Xu, Y Qiu, J Wang, L Meng - Progress in Materials Science, 2024 - Elsevier
In recent decades, cyclotriphosphazene (CTP) and its derivatives have garnered significant
attention due to their exceptional physical and chemical properties, such as remarkable …

Chiral configurations in cyclophosphazene chemistry

A Uslu, S Yeşilot - Coordination Chemistry Reviews, 2015 - Elsevier
The pentavalent phosphorus atoms in cyclophosphazenes (NPXY) n are tetra-coordinated
and their potential centers of chirality are analogous to those for tetrahedral carbon …

Tetrakis (hydroxymethyl) phosphonium salts: Their properties, hazards and toxicities

DV Moiseev, BR James - Phosphorus, Sulfur, and Silicon and the …, 2020 - Taylor & Francis
Tetrakis (hydroxymethyl) phosphonium chloride (THPC) and sulfate (THPS) are of
importance in the textile industry as flame retardants, in the oil industry as scale-removers …

Phosphorus− Nitrogen Compounds. 18. Syntheses, stereogenic properties, structural and electrochemical investigations, biological activities, and DNA interactions of …

N Asmafiliz, Z Kılıç, A Öztürk, T Hökelek… - Inorganic …, 2009 - ACS Publications
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6, with mono-(1 and 2) and
bisferrocenyldiamines (3− 5), FcCH2NH (CH2) n NHR1 (R1= H or FcCH2−), produce mono …

Ring-closing metathesis reactions of terminal alkene-derived cyclic phosphazenes

D Kumar, N Singh, K Keshav, AJ Elias - Inorganic Chemistry, 2011 - ACS Publications
The first examples of ring-closing metathesis (RCM) reactions of a series of terminal alkene-
derived cyclic phosphazenes have been carried out. The tetrakis-, hexakis-, and octakis …

Phospha-Mannich reactions of PH3 and its analogs

DV Moiseev, BR James - Phosphorus, Sulfur, and Silicon and the …, 2022 - Taylor & Francis
The easiest route to form compounds with P–C sp3–N linkage (s) is phosphorus-based
Mannich-type reactions (phospha-Mannich reactions) between phosphines (R3P, R2PH …

Synthesis and reactions of ethynylferrocene-derived fluoro-and chlorocyclotriphosphazenes

K Keshav, N Singh, AJ Elias - Inorganic chemistry, 2010 - ACS Publications
The reactions of lithiated ethynylferrocene, FcC CLi (Fc= ferrocenyl), with fluoro-and
chlorocyclotriphosphazenes, N3P3X6 (X= F, Cl), resulted in the formation of stable mono …

Competitive formation of spiro and ansa derivatives in the reactions of tetrafluorobutane-1, 4-diol with hexachlorocyclotriphosphazene: A comparison with butane-1, 4 …

S Beşli, SJ Coles, DB Davies, RJ Eaton, A Kılıç… - Polyhedron, 2006 - Elsevier
Reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (1), in two stoichiometries (1: 1.2 and
1: 3) with the sodium derivative of the fluorinated diol, 2, 2, 3, 3-tetrafluorobutane-1, 4-diol …

Ansa versus spiro substitution of cyclophosphazenes: Is fluorination essential for ansa to spiro transformation of cyclophosphazenes?

K Muralidharan, P Venugopalan, AJ Elias - Inorganic chemistry, 2003 - ACS Publications
Fluorinated ansa substituted cyclophosphazenes endo-FcCH2P (S)(CH2O) 2 [P (F) N] 2
(F2PN)[Fc= ferrocenyl](1) and exo-FcCH2P (S)(CH2O) 2 [P (F) N] 2 (F2PN)(2) readily …

Single-, double-and triple-bridged derivatives of cyclotriphosphazenes with an octafluorohexane-1, 6-diol

S Beşli, SJ Coles, DB Davies, AO Erkovan… - Polyhedron, 2009 - Elsevier
Reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (1), with the sodium derivative of the
fluorinated diol, 2, 2, 3, 3, 4, 4, 5, 5-octafluorohexane-1, 6-diol,(2), in THF solution at room …