Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

R Zhang, Y Wang, Y Zhao, C Redshaw… - Dalton …, 2021 - pubs.rsc.org
α-Diimine ligands, in particular 1, 4-diazabutadiene (dad) and bis (iminoacenaphthene)(
bian) derivatives, have been widely used for coordination with various metals, including …

A quarter-century long story of bis (alkyl) rare-earth (III) complexes

AA Trifonov, DM Lyubov - Coordination Chemistry Reviews, 2017 - Elsevier
A quarter-century long story of bis(alkyl) rare-earth (III) complexes - ScienceDirect Skip to main
contentSkip to article Elsevier logo Journals & Books Search RegisterSign in View PDF …

Thermally Stable Ln (II) and Ca (II) Bis (benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C–C Multiple Bonds

AN Selikhov, GS Plankin, AV Cherkasov… - Inorganic …, 2019 - ACS Publications
A series of Ln (II) and Ca (II) bis (alkyl) complexes with bulky benzhydryl ligands,[(pt Bu-
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …

Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination

AA Kissel, TV Mahrova, DM Lyubov… - Dalton …, 2015 - pubs.rsc.org
Metallacyclic neutral and ionic yttrium alkyl complexes coordinated by a dianionic ene-
diamido ligand ([2, 6-iPr2C6H3NC (Me) C (Me) NC6H3iPr2-2, 6]= L1)[L1] Y …

Chemistry of s-, p-and f-block metal complexes with ene-diamido ligands

Y Bai, W Chen, J Li, C Cui - Coordination Chemistry Reviews, 2019 - Elsevier
The α-ene-diamido ligands (the reduced form of α-diimine) have been extensively studied
as supporting ligands for s-, p-and f-block elements over the last several decades. They not …

Chemistry of diazadiene type ligands with extra coordination groups. Prospects of reactivity

EN Nikolaevskaya, NO Druzhkov… - Coordination Chemistry …, 2020 - Elsevier
Abstract N= C–C= N backbone ligands have been extensively studied for s-, p-, d-and f-
block elements over the last several decades. Their diverse bonding modes and redox …

Ln (II) alkyl complexes: from elusive exotics to catalytic applications

DM Lyubov, AA Trifonov - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Ln( ii ) alkyl complexes: from elusive exotics to catalytic applications - Inorganic Chemistry
Frontiers (RSC Publishing) DOI:10.1039/D1QI00206F Royal Society of Chemistry View PDF …

Tris (benzhydryl) and Cationic Bis (benzhydryl) Ln (III) Complexes: Exceptional Thermostability and Catalytic Activity in Olefin Hydroarylation and Hydrobenzylation …

AN Selikhov, EN Boronin, AV Cherkasov… - Advanced Synthesis …, 2020 - Wiley Online Library
A series of Ln (III) tris (benzhydryl) complexes [(p‐tBu‐C6H4) 2CH] 3Ln (Ln= La (1), Nd (2),
Y (3)) were synthesized by the salt metathesis reactions of LnHal3 (THF) 3.5 (Ln= La, Nd …

Activation of Ene-Diamido Samarium Methoxide with Hydrosilane for Selectively Catalytic Hydrosilylation of Alkenes and Polymerization of Styrene: an Experimental …

J Li, C Zhao, J Liu, H Huang, F Wang, X Xu… - Inorganic …, 2016 - ACS Publications
Samarium methoxide incorporating the ene-diamido ligand L (DME) Sm (μ-OMe) 2Sm
(DME) L (1; L=[DipNC (Me) C (Me) NDip] 2–, Dip= 2, 6-i Pr2C6H3, and DME= 1, 2 …