Solar utilization beyond photosynthesis

J Lv, J Xie, AGA Mohamed, X Zhang, Y Feng… - Nature Reviews …, 2023 - nature.com
Natural photosynthesis is an efficient biochemical process which converts solar energy into
energy-rich carbohydrates. By understanding the key photoelectrochemical processes and …

Metalloporphyrins as catalytic models for studying hydrogen and oxygen evolution and oxygen reduction reactions

X Li, H Lei, L Xie, N Wang, W Zhang… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and
oxygen reduction reaction (ORR) are involved in biological and artificial energy conversions …

Structural evidence for intermediates during O2 formation in photosystem II

A Bhowmick, R Hussein, I Bogacz, PS Simon… - Nature, 2023 - nature.com
In natural photosynthesis, the light-driven splitting of water into electrons, protons and
molecular oxygen forms the first step of the solar-to-chemical energy conversion process …

Unraveling Sequential Oxidation Kinetics and Determining Roles of Multi-Cobalt Active Sites on Co3O4 Catalyst for Water Oxidation

W Kang, R Wei, H Yin, D Li, Z Chen… - Journal of the …, 2023 - ACS Publications
The multi-redox mechanism involving multi-sites has great implications to dictate the
catalytic water oxidation. Understanding the sequential dynamics of multi-steps in oxygen …

Serial femtosecond crystallography

TRM Barends, B Stauch, V Cherezov… - Nature reviews Methods …, 2022 - nature.com
With the advent of X-ray free-electron lasers (XFELs), new, high-throughput serial
crystallography techniques for macromolecular structure determination have emerged …

On the origin of multihole oxygen evolution in haematite photoanodes

G Righi, J Plescher, FP Schmidt, RK Campen… - Nature Catalysis, 2022 - nature.com
The oxygen evolution reaction (OER) plays a crucial role in (photo) electrochemical devices
that use renewable energy to produce synthetic fuels. Recent measurements on …

Light harvesting in oxygenic photosynthesis: Structural biology meets spectroscopy

R Croce, H van Amerongen - Science, 2020 - science.org
BACKGROUND The harvesting of photons is the first step in photosynthesis, the biological
process that transforms solar energy into chemical energy. The photosynthetic membranes …

Solar energy conversion by photosystem II: principles and structures

D Shevela, JF Kern, G Govindjee, J Messinger - Photosynthesis research, 2023 - Springer
Photosynthetic water oxidation by Photosystem II (PSII) is a fascinating process because it
sustains life on Earth and serves as a blue print for scalable synthetic catalysts required for …

Iron and manganese oxo complexes, oxo wall and beyond

VA Larson, B Battistella, K Ray, N Lehnert… - Nature Reviews …, 2020 - nature.com
High-valent metal–oxo species with multiply-bonded M–O groups have been proposed as
key intermediates in many biological and abiological catalytic oxidation reactions. These …

Advances and challenges in time-resolved macromolecular crystallography

G Brändén, R Neutze - Science, 2021 - science.org
BACKGROUND Conformational changes are essential for the correct functioning of
biological macromolecules. Time-resolved x-ray crystallography extends an extremely …