The Nitrogen Bond, or the Nitrogen-Centered Pnictogen Bond: The Covalently Bound Nitrogen Atom in Molecular Entities and Crystals as a Pnictogen Bond Donor
The nitrogen bond in chemical systems occurs when there is evidence of a net attractive
interaction between the electrophilic region associated with a covalently or coordinately …
interaction between the electrophilic region associated with a covalently or coordinately …
Nitrogen in black phosphorus structure
Group V elements in crystal structure isostructural to black phosphorus with unique
puckered two-dimensional layers exhibit exciting physical and chemical phenomena …
puckered two-dimensional layers exhibit exciting physical and chemical phenomena …
Aromatic hexazine [N6]4− anion featured in the complex structure of the high-pressure potassium nitrogen compound K9N56
The recent high-pressure synthesis of pentazolates and the subsequent stabilization of the
aromatic [N5]− anion at atmospheric pressure have had an immense impact on nitrogen …
aromatic [N5]− anion at atmospheric pressure have had an immense impact on nitrogen …
Remarkable stability of - and its prevalence in the nitrogen phase diagram
Solid nitrogen exhibits a panoply of phenomena ranging from complex molecular crystalline
configurations to polymerization and closing band gap at higher densities. Among the …
configurations to polymerization and closing band gap at higher densities. Among the …
Prediction of stable iron nitrides at ambient and high pressures with progressive formation of new polynitrogen species
Nitride materials are of considerable interest due to their fundamental importance and
practical applications. However, synthesis of transition metal nitrides often requires extreme …
practical applications. However, synthesis of transition metal nitrides often requires extreme …
Structure determination of ζ-N2 from single-crystal X-ray diffraction and theoretical suggestion for the formation of amorphous nitrogen
The allotropy of solid molecular nitrogen is the consequence of a complex interplay between
fundamental intermolecular as well as intramolecular interactions. Understanding the …
fundamental intermolecular as well as intramolecular interactions. Understanding the …
Materials under high pressure: a chemical perspective
At high pressure, the typical behavior of elements dictated by the periodic table—including
oxidation numbers, stoichiometries in compounds, and reactivity, to name but a few—is …
oxidation numbers, stoichiometries in compounds, and reactivity, to name but a few—is …
Revealing Phosphorus Nitrides up to the Megabar Regime: Synthesis of α′‐P3N5, δ‐P3N5 and PN2
Non‐metal nitrides are an exciting field of chemistry, featuring a significant number of
compounds that can possess outstanding material properties. These properties mainly rely …
compounds that can possess outstanding material properties. These properties mainly rely …
Creating Cyclo-N5+ Cations and Assembling N5+N5– Salts via Electronegativity Comatching in Tailored Ionic Compounds
The recent discovery of crystalline pentazolates marks a major advance in polynitrogen
chemistry and raises prospects of making the long-touted potent propellant N5+ N5–salt …
chemistry and raises prospects of making the long-touted potent propellant N5+ N5–salt …
High-Pressure Synthesis of the β-Zn3N2 Nitride and the α-ZnN4 and β-ZnN4 Polynitrogen Compounds
D Laniel, AA Aslandukova, AN Aslandukov… - Inorganic …, 2021 - ACS Publications
High-pressure nitrogen chemistry has expanded at a formidable rate over the past decade,
unveiling the chemical richness of nitrogen. Here, the Zn-N system is investigated in laser …
unveiling the chemical richness of nitrogen. Here, the Zn-N system is investigated in laser …