We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

The chemical activation of water would allow this earth-abundant resource to be transferred
into value-added compounds, and is a topic of keen interest in energy research,. Here, we …

Non-equilibrium atmospheric-pressure plasmas have recently become a topical area of
research owing to their diverse applications in health care and medicine, environmental …

Aqueous rechargeable zinc ion batteries have attracted increased attention for large-scale
energy storage owing to their cost-effectiveness, safety and high volumetric energy density …

Unactivated olefins are converted to alkyl azides with bench-stable NaN3 in the presence of
FeCl3· 6H2O under blue-light irradiation. The products are obtained with anti-Markovnikov …

The oxidation of syngas mixtures was investigated experimentally and simulated with an
updated chemical kinetic model. Ignition delay times for H2/CO/O2/N2/Ar mixtures have …

A new molecular spectroscopic database for high-temperature modeling of the spectra of
molecules in the gas phase is described. This database, called HITEMP, is analogous to the …

Many, if not most, redox reactions are coupled to proton transfers. This includes most
common sources of chemical potential energy, from the bioenergetic processes that power …

Coordination-induced bond weakening is a phenomenon wherein ligand X–H bond
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …