The study of singlet molecular oxygen production and reactivity has emerged as a rich and diverse area with implications in fields ranging from polymer science to cancer therapy. In …
C Schweitzer, R Schmidt - Chemical reviews, 2003 - ACS Publications
For more than 70 years, researchers in several areas of science have been intrigued by the physical and chemical properties of the lowest excited states of molecular oxygen. With two …
The photooxidation of a mustard‐gas simulant, 2‐chloroethyl ethyl sulfide (CEES), is studied using a porphyrin‐based metal–organic framework (MOF) catalyst. At room temperature and …
R Schmidt - Photochemistry and photobiology, 2006 - Wiley Online Library
This work gives an overview of what is currently known about the mechanisms of the photosensitized production of singlet oxygen. Quenching of ππ* excited triplet states by O2 …
The endoperoxides of β-carotene (βCar-EPOs) are regarded as main products of the chemical deactivation of 1O2 by β-carotene, one of the most important antioxidants …
J Wu, J Chen, L Wang, H Zhu, R Liu, G Song… - Green …, 2023 - pubs.rsc.org
Photo-oxygenation represents an appealing strategy for the effective production of high value-added carbonyls by directly manipulating the ubiquitous C–H bonds. Nevertheless …
SP Pitre, CD McTiernan, W Vine, R DiPucchio… - Scientific reports, 2015 - nature.com
Photoredox catalysis provides many green opportunities for radical-mediated synthetic transformations. However, the determination of the underlying mechanisms has been …
Hydantoins are important scaffolds in natural products and pharmaceuticals, with only a few synthetic strategies available for their asymmetric preparation. We herein describe a single …
AA Abdel-Shafi, PD Beer, RJ Mortimer… - The Journal of …, 2000 - ACS Publications
Photophysical properties of 10 substituted methoxybenzene or vinyl linked benzo-crown- ether− 2, 2 '-bipyridyl ruthenium (II) complexes are reported. The lifetimes of the excited …