Lanthanide probes for bioresponsive imaging

MC Heffern, LM Matosziuk, TJ Meade - Chemical reviews, 2014 - ACS Publications
The chemistry of the less familiar elements is a fascinating topic especially for the inorganic
minded. The lanthanides, or rare earths, comprise the 5d block of the periodic table and …

Photosensitized singlet oxygen and its applications

MC DeRosa, RJ Crutchley - Coordination chemistry reviews, 2002 - Elsevier
The study of singlet molecular oxygen production and reactivity has emerged as a rich and
diverse area with implications in fields ranging from polymer science to cancer therapy. In …

Physical mechanisms of generation and deactivation of singlet oxygen

C Schweitzer, R Schmidt - Chemical reviews, 2003 - ACS Publications
For more than 70 years, researchers in several areas of science have been intrigued by the
physical and chemical properties of the lowest excited states of molecular oxygen. With two …

Selective photooxidation of a mustard‐gas simulant catalyzed by a porphyrinic metal–organic framework

Y Liu, AJ Howarth, JT Hupp, OK Farha - Angewandte Chemie, 2015 - Wiley Online Library
The photooxidation of a mustard‐gas simulant, 2‐chloroethyl ethyl sulfide (CEES), is studied
using a porphyrin‐based metal–organic framework (MOF) catalyst. At room temperature and …

Photosensitized generation of singlet oxygen

R Schmidt - Photochemistry and photobiology, 2006 - Wiley Online Library
This work gives an overview of what is currently known about the mechanisms of the
photosensitized production of singlet oxygen. Quenching of ππ* excited triplet states by O2 …

Triplet-driven chemical reactivity of β-carotene and its biological implications

M Zbyradowski, M Duda, A Wisniewska-Becker… - Nature …, 2022 - nature.com
The endoperoxides of β-carotene (βCar-EPOs) are regarded as main products of the
chemical deactivation of 1O2 by β-carotene, one of the most important antioxidants …

Brønsted acid-catalysed aerobic photo-oxygenation of benzylic C–H bonds

J Wu, J Chen, L Wang, H Zhu, R Liu, G Song… - Green …, 2023 - pubs.rsc.org
Photo-oxygenation represents an appealing strategy for the effective production of high
value-added carbonyls by directly manipulating the ubiquitous C–H bonds. Nevertheless …

Visible-Light Actinometry and Intermittent Illumination as Convenient Tools to Study Ru(bpy)3Cl2 Mediated Photoredox Transformations

SP Pitre, CD McTiernan, W Vine, R DiPucchio… - Scientific reports, 2015 - nature.com
Photoredox catalysis provides many green opportunities for radical-mediated synthetic
transformations. However, the determination of the underlying mechanisms has been …

Enantioselective synthesis of hydantoins by chiral acid-catalysed condensation of glyoxals and ureas

S Aryal, CA Hone, MIJ Polson, DJ Foley - Chemical Science, 2023 - pubs.rsc.org
Hydantoins are important scaffolds in natural products and pharmaceuticals, with only a few
synthetic strategies available for their asymmetric preparation. We herein describe a single …

Photosensitized generation of singlet oxygen from vinyl linked benzo-crown-ether− bipyridyl ruthenium (II) complexes

AA Abdel-Shafi, PD Beer, RJ Mortimer… - The Journal of …, 2000 - ACS Publications
Photophysical properties of 10 substituted methoxybenzene or vinyl linked benzo-crown-
ether− 2, 2 '-bipyridyl ruthenium (II) complexes are reported. The lifetimes of the excited …