The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …

The Brook rearrangement has emerged as one of the most pivotal transformations in organic
chemistry, with broad applications spanning organic synthesis, drug design, and materials …

This research explores the enantioselective hydrosulfonylation of various α, β‐unsaturated
carbonyl compounds via the use of visible light and redox‐active chiral Ni‐catalysis …

The electrochemical synthesis of fluorinated allyl silanes and boronates was disclosed. The
addition of electrogenerated boryl or silyl radicals onto many α‐trifluoromethyl or α …

Ketyl radicals are valuable reactive intermediates because they allow carbonyl chemistry to
be extended beyond traditional electrophilic reactivity through simple single-electron …

The gem-difluoroalkene framework is an important unit because of its presence in many
biologically active natural products. Herein, we report a visible-light-promoted radical [1, 2] …

Herein, an operationally simple and mild protocol for defluorinative alkylation and arylation
between thianthrenium salts and α-trifluoromethyl alkene with visible light to afford gem …

Herein, we report a photoredox enabled defluorinative benzylation of trifluoromethyl alkenes
with readily available alkylarenes, which provides convenient access to a series of …

Herein, we disclose a general method for the assembly of C-allyl glycosides containing gem-
difluoroalkene groups via a radical-polar crossover strategy. Central to the success of this …