Steroids: reactions and partial synthesis

JR Hanson - Natural product reports, 2005 - pubs.rsc.org
Covering: January to December 2003 This article reviews the progress in the chemistry of
the steroids that was published between January and December 2003. The reactions and …

Synthesis of 26-hydroxy-22-oxocholestanic frameworks from diosgenin and hecogenin and their in vitro antiproliferative and apoptotic activity on human cervical …

MA Fernández-Herrera, H López-Muñoz… - Bioorganic & Medicinal …, 2010 - Elsevier
Certain steroidal compounds have demonstrated an antiproliferative effect against several
tumor cell lines; however, their complete role on cancer cells is not currently established …

Synthesis of steroidal derivatives containing substituted, fused and spiro pyrazolines

A Romero-López, S Montiel-Smith, S Meza-Reyes… - Steroids, 2014 - Elsevier
An efficient and facile synthesis of fused, substituted and spiro pyrazoline steroid derivatives
through a cycloaddition reaction of different α, β-unsaturated ketones with hydrazine acetate …

Abnormal Beckmann rearrangement in 23-hydroxyiminodiosgenin acetate

MA Iglesias-Arteaga, J Sandoval-Ramırez… - Tetrahedron letters, 2004 - Elsevier
A new transformation of the spiroketal side chain of diosgenin is reported: treatment of 23-
hydroxyiminodiosgenin acetate with phosphorous oxychloride in pyridine produced an …

A new route for the preparation of the 22, 23-dioxocholestane side chain from diosgenin and its application to the stereocontrolled construction of the 22R, 23S-diol …

S Rincón, RE del Río, J Sandoval-Ramírez… - Tetrahedron, 2006 - Elsevier
The new (22R, 23S, 25R)-3β, 16β, 26-triacetoxy-cholest-5-ene-22, 23-diol () was
synthesized from diosgenin () through a synthetic route based on chemoselective RuO4 …

Side-chain opening of steroidal sapogenins to form 22-oxocholestanic skeletons: An approach to analogues of the aglycone of the potent anticancer agent OSW-1

MA Fernández-Herrera, J Sandoval-Ramírez… - Journal of the Mexican …, 2009 - scielo.org.mx
The side–chain opening of 25R and 25S steroidal sapogenins to form 22–oxocholestanic
skeletons is described. The transformation was produced under mild conditions providing …

Favorskii rearrangement of 23-oxo-3-epi-smilagenin acetate induced by iodosobenzene

MA Iglesias-Arteaga, GA Velázquez-Huerta - Tetrahedron letters, 2005 - Elsevier
Favorskii rearrangement of 23-oxo-3-epi-smilagenin acetate induced by iodosobenzene -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

One-step axial acetoxylation at C-23. A new method for the functionalization of the side chain of steroid sapogenins

MA Iglesias-Arteaga, RO Arcos-Ramos - Tetrahedron letters, 2006 - Elsevier
One-step axial acetoxylation at C-23. A new method for the functionalization of the side
chain of steroid sapogenins - ScienceDirect Skip to main contentSkip to article Elsevier logo …

Green chemistry approaches to the synthesis of pyrazoline steroid derivatives and their theoretical DFT characterization

MEC Sánchez, L Noriega, JM Perez-Aguilar… - Green Chemistry and …, 2022 - Elsevier
Pyrazoline steroids are electron-rich nitrogen-containing heterocyclic structures that exhibit
several desirable pharmacological features. Conventional synthetic techniques to obtain …

[PDF][PDF] The Baeyer-Villiger reaction of 23-oxosapogenins

MA Iglesias-Arteaga, GA Velázquez-Huerta… - Arkivoc, 2005 - arkat-usa.org
Abstract The Baeyer-Villiger reactions of 25R-and 25S-23-oxosapogenins with MCPBA
produced a mixture of bisnorcholanic 22→ 16 lactones and pregnan-16, 20-diol carbonates …