The crucial role of silver (i)-salts as additives in C–H activation reactions: overall analysis of their versatility and applicability

RL de Carvalho, EBT Diogo, SL Homölle… - Chemical Society …, 2023 - pubs.rsc.org
Transition-metal catalyzed C–H activation reactions have been proven to be useful
methodologies for the assembly of synthetically meaningful molecules. This approach bears …

Transition metal-catalysed directed C–H functionalization with nucleophiles

S Barranco, J Zhang, S López-Resano, A Casnati… - Nature …, 2022 - nature.com
The quest for sustainable ways to introduce diverse functional groups onto complex
scaffolds has made directed transition metal-catalysed C–H functionalization reactions a …

Deciphering the role of silver in palladium-catalyzed C–H functionalizations

T Bhattacharya, S Dutta, D Maiti - ACS Catalysis, 2021 - ACS Publications
Over the years, silver salts have become an integral part of palladium-catalyzed C–H
functionalization. Although most of the research works highlight the role of Ag (I) complexes …

Decarbonylative fluoroalkylation at palladium (II): from fundamental organometallic studies to catalysis

N Lalloo, CA Malapit, SM Taimoory… - Journal of the …, 2021 - ACS Publications
This Article describes the development of a decarbonylative Pd-catalyzed aryl–fluoroalkyl
bond-forming reaction that couples fluoroalkylcarboxylic acid-derived electrophiles [RFC (O) …

Bimetallic Pd–Ag nanoclusters decorated micro-cellulose bio-template towards efficient catalytic Suzuki–Miyaura coupling reaction of nitrogen-rich heterocycles

P Bhattacharjee, A Dewan, PK Boruah, MR Das… - Green …, 2022 - pubs.rsc.org
Cellulose fibers (width 8 μm) were extracted from the waste feedstock of pomegranate peels
in a simple filtration method using a water–ethanol system, without any harsh chemical pre …

Transition Metal‐Catalyzed C− H Functionalization Through Electrocatalysis

PK Baroliya, M Dhaker, S Panja… - …, 2023 - Wiley Online Library
Electrochemically promoted transition metal‐catalyzed C− H functionalization has emerged
as a promising area of research over the last few decades. However, development in this …

Palladium‐Catalyzed Electrophilic Functionalization of Pyridine Derivatives through Phosphonium Salts

YY Che, Y Yue, LZ Lin, B Pei, X Deng… - Angewandte Chemie …, 2020 - Wiley Online Library
Herein, we report a highly efficient and practical method for pyridine‐derived heterobiaryl
synthesis through palladium‐catalyzed electrophilic functionalization of easily available …

Pd-catalyzed site-selective C (sp 2)–H radical acylation of phenylalanine containing peptides with aldehydes

M San Segundo, A Correa - Chemical Science, 2019 - pubs.rsc.org
The site-selective functionalization of C–H bonds within a peptide framework remains a
challenging task of prime synthetic importance. Herein, the first Pd-catalyzed δ-C (sp2)–H …

Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization

G Athavan, TFN Tanner, AC Whitwood… - …, 2022 - ACS Publications
Increasing evidence indicates that silver salts can play a role in the C–H activation step of
palladium-catalyzed C–H functionalization. Here we isolate a silver (I) complex by C–H …

Weinreb amides as directing groups for transition metal-catalyzed CH functionalizations

J Kalepu, LT Pilarski - Molecules, 2019 - mdpi.com
Weinreb amides are a privileged, multi-functional group with well-established utility in
classical synthesis. Recently, several studies have demonstrated the use of Weinreb amides …