This chapter points out significant advances in the asymmetric synthesis of P-chiral
organophosphorus compounds with many applications in stereoselective synthesis and in …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

The palladium-catalyzed unified approach using in situ-generated Phospha-TMM species to
synthesize a diverse array of chiral organophosphorus containing carbo-and heterocyclic …

2, 5-Diferrocenyl-1-phenyl-1 H-phosphole (3) has successfully been prepared by a
cyclization reaction of phenylphosphine with 1, 4-diferrocenyl butadiyne. Subsequent …

Sulfur-protected enantiopure P-chiral 1-phosphanorbornane silyl ethers 5a, b are obtained
in high yields via the reaction of the hydroxy group of P-chiral 1-phosphanorbornane alcohol …

The heavier main group multiple bonds offer an effective tool for small molecule activation.
Transient 2H‐phosphinidole working as a reactive phosphadiene system undergoes …

The reactive P− N bond in a racemic mixture of endo‐1‐phospha‐2‐azanorbornene
(PAN)(RP/SP)‐endo‐1 is readily cleaved with enantiomerically pure lithium alkoxides …

A convenient synthesis of enantiopure mixed donor phosphine–phosphite ligands has been
developed incorporating P-stereogenic phosphanorbornane and axially chiral bisnaphthols …

The phospha-Diels–Alder reaction between 2H-phospholes and arylallenes affords 6-
methylene-1-phosphanorbornenes in high yields with excellent regioselectivity. This Diels …

A straightforward synthesis of P-chiral polycyclic phosphines by an asymmetric Diels–Alder
reaction of 1-alkyl-1, 2-diphospholes and (5R)-(L-menthyloxy)-2 (5H)-furanone (MOxF) is …