[HTML][HTML] Reactivities and mechanisms in organic reactions involving activation of elemental sulfur under basic conditions

P Conen, MAR Meier - Tetrahedron Chem, 2024 - Elsevier
As a readily available and benign waste product of the petrochemical industry, elemental
sulfur displays desirable characteristics as a raw material for new processes. Accordingly …

DABCO-Catalyzed DMSO-Promoted Sulfurative 1,2-Diamination of Phenylacetylenes with Elemental Sulfur and o-Phenylenediamines: Access to Quinoxaline-2 …

TMC Tran, ND Lai, TTT Bui, DH Mac, TTT Nguyen… - Organic …, 2023 - ACS Publications
The oxidative amination of alkynes typically requires transition metal catalysts and strong
oxidants. Herein, we alternatively utilize DABCO as a sulfur-activating catalyst to achieve the …

Pushing Boundaries: What's Next in Metal-Free C–H Functionalization for Sulfenylation?

P Rani, S Chahal, R Singh, J Sindhu - Topics in Current Chemistry, 2024 - Springer
The synthesis of thioether derivatives has been explored widely due to the potential
application of these derivatives in medicinal chemistry, pharmaceutical industry and material …

Three-Component Reaction between 3-Acetylcoumarins, Amines, and Elemental Sulfur: A Designed Approach to 3-Amino-4H-thieno[3,2-c]coumarins

B Farajpour, R Heydarzadeh… - The Journal of …, 2024 - ACS Publications
In this work, a series of novel 3-amino-4 H-thieno [3, 2-c] coumarins were designed and
synthesized by a one-pot, catalyst-free, and three-component reaction of 3-acetylcoumarins …

Sulfur-Promoted Oxidative Condensation of Chalcones with Unsubstituted Cyanoacetamide in DMSO: Access to 3-Cyanopyrid-2-ones

BN Nguyen, MH Tran, TTT Bui, DH Mac… - The Journal of …, 2023 - ACS Publications
Sulfur-Promoted Oxidative Condensation of Chalcones with Unsubstituted Cyanoacetamide in
DMSO: Access to 3-Cyanopyrid-2-ones | The Journal of Organic Chemistry ACS ACS …

Sulfur-Promoted Access to 3-Arylquinoxalin-2-ones by Oxidative Coupling of o-Phenylenediamines with Arylacetates

LA Nguyen, TY Tran, QA Ngo, DH Mac… - Organic …, 2024 - ACS Publications
We disclose the synthesis of 3-arylquinoxalin-2-ones from o-phenylenediamines and readily
available arylacetates. The method harnesses the selective oxidative property of elemental …

Sulfur-and DABCO-Promoted Reaction between Alkylidene Rhodanines and Isothiocyanates: Access to Aminoalkylidene Rhodanines

B Farajpour, GB Alizadeh, S Majedi, F Moradkhani… - ACS …, 2024 - ACS Publications
In this work, an efficient sulfur-and DABCO-promoted reaction for the synthesis of
aminoalkylidene rhodanines from available alkylidene rhodanines and isothiocyanates is …

Novel Catalyst-Free Synthesis of Some 3-Alkylaminoquinoxaline-2(1H)-thiones and 3-Alkyloxyquinoxaline-2(1H)-thiones in Ethanol

SM El Rayes, IAI Ali, W Fathalla, MA Ghanem… - ACS …, 2025 - ACS Publications
Seventeen 3-alkylaminoquinoxaline-2 (1 H)-thiones and 3-alkyloxyquinoxaline-2 (1 H)-
thiones were prepared by a novel thionation protocol from the readily available quinoxaline …

Sodium sulfide-promoted regiodefined redox condensation of o-nitroanilines with aryl ketones to benzo [a] phenazines and quinoxalines

DL Le, NB Vo, TTT Nguyen, QA Ngo… - Organic & …, 2024 - pubs.rsc.org
Inexpensive sodium sulfide trihydrate was found to promote unprecedented 6e-regio-
predefined redox condensation of o-nitroanilines with α-tetralones to benzo [a] phenazines …

Multicomponent Reaction for the Synthesis of Quinoxalin-2-Thiones and Quinoxalines

P Richardson, TP Montgomery - Synfacts, 2023 - thieme-connect.com
Significance: Quinoxalines represent a privileged group of nitrogen-containing heterocycles
and have found wide use in medicinal chemistry and material science. An interesting subset …