Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Challenges to developing materials for the transport and storage of hydrogen
Hydrogen has the highest gravimetric energy density of any energy carrier and produces
water as the only oxidation product, making it extremely attractive for both transportation and …
water as the only oxidation product, making it extremely attractive for both transportation and …
Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
Recent advances in process engineering and upcoming applications of metal–organic frameworks
Progress in metal–organic frameworks (MOFs) has advanced from fundamental chemistry to
engineering processes and applications, resulting in new industrial opportunities. The …
engineering processes and applications, resulting in new industrial opportunities. The …
Directional shunting of photogenerated carriers in POM@ MOF for promoting nitrogen adsorption and oxidation
X Li, L Yang, Q Liu, W Bai, H Li, M Wang… - Advanced …, 2023 - Wiley Online Library
The efficient catalysis of nitrogen (N2) into high‐value N‐containing products plays a crucial
role in the N economic cycle. However, weak N2 adsorption and invalid N2 activation …
role in the N economic cycle. However, weak N2 adsorption and invalid N2 activation …
Tuning Coordination Structures of Zn Sites Through Symmetry‐Breaking Accelerates Electrocatalysis
Manipulating the coordination environment of individual active sites in a precise manner
remains an important challenge in electrocatalytic reactions. Herein, inspired by theoretical …
remains an important challenge in electrocatalytic reactions. Herein, inspired by theoretical …
Recent progress on microfine design of metal–organic frameworks: structure regulation and gas sorption and separation
Metal–organic frameworks (MOFs) have emerged as an important and unique class of
functional crystalline hybrid porous materials in the past two decades. Due to their modular …
functional crystalline hybrid porous materials in the past two decades. Due to their modular …
Separation and purification of hydrocarbons with porous materials
Y Wu, BM Weckhuysen - Angewandte Chemie International …, 2021 - Wiley Online Library
This Minireview focuses on the developments of the adsorptive separation of
methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of …
methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of …
Metal-organic frameworks composed of nitro groups: Preparation and applications in adsorption and catalysis
In this review, metal–organic frameworks functionalized with nitro groups (MOF-NO 2 s)
were analyzed, for the first time, in terms of their preparation and applications. MOF-NO 2 s …
were analyzed, for the first time, in terms of their preparation and applications. MOF-NO 2 s …
Pore space partition of metal-organic frameworks for gas storage and separation
Pore space partition (PSP) concept is a synthetic design concept and can also serve as a
structure analysis method useful for next-step synthetic planning and execution. PSP …
structure analysis method useful for next-step synthetic planning and execution. PSP …