Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

BM Trost, CA Kalnmals - Chemistry–A European Journal, 2019 - Wiley Online Library
Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even
radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl …

Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

L Marzo, SK Pagire, O Reiser, B König - Angewandte Chemie, 2018 - Wiley Online Library
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …

Stereocontrolled Synthesis of 1, 4‐Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals

G Goti, B Bieszczad, A Vega‐Peñaloza… - Angewandte Chemie …, 2019 - Wiley Online Library
We report a visible‐light‐mediated organocatalytic strategy for the enantioselective acyl
radical conjugate addition to enals, leading to valuable 1, 4‐dicarbonyl compounds. The …

Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities

PHY Cheong, CY Legault, JM Um… - Chemical …, 2011 - ACS Publications
Organocatalysis has captured the imagination of a significant group of synthetic chemists.
Much of the mechanistic understanding of these reactions has come from computational …

[HTML][HTML] Recent advances in the synthesis of vinyl sulfones

Y Fang, Z Luo, X Xu - RSC advances, 2016 - pubs.rsc.org
Development of the methodology for the preparation of vinyl sulfones is of significant interest
to organic chemists. Recently, numerous useful methods have been developed, mainly …

Visible Light‐Mediated Metal‐Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

AU Meyer, S Jäger, D Prasad Hari… - Advanced Synthesis & …, 2015 - Wiley Online Library
Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and
alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes …

Phenanthroline-initiated anti-selective hydrosulfonylation of unactivated alkynes with sulfonyl chlorides

CS Dong, WY Tong, P Ye, N Cheng, S Qu… - ACS Catalysis, 2023 - ACS Publications
A simple and general method for anti-selective hydrosulfonylation of unactivated alkynes
with sulfonyl chlorides in the presence of a catalytic amount of phenanthroline-based Lewis …

Copper (I)-catalyzed sulfonylation of 8-aminoquinoline amides with sulfonyl chlorides in air

H Qiao, S Sun, F Yang, Y Zhu, W Zhu, Y Dong… - Organic …, 2015 - ACS Publications
A simple and mild protocol for copper (I)-mediated sulfonylation of 8-aminoquinoline amides
with sulfonyl chlorides was developed, affording desired products in moderate to good …

Asymmetric organocatalysis with sulfones

M Nielsen, CB Jacobsen, N Holub… - Angewandte Chemie …, 2010 - Wiley Online Library
Asymmetric organocatalysis has become a powerful tool for the synthesis of optically active
compounds. Whereas early research mainly focused on combining simple reagents as a …