Chemical diversity for tailoring negative thermal expansion

Q Li, K Lin, Z Liu, L Hu, Y Cao, J Chen… - Chemical Reviews, 2022 - ACS Publications
Negative thermal expansion (NTE), referring to the lattice contraction upon heating, has
been an attractive topic of solid-state chemistry and functional materials. The response of a …

Negative Poisson's ratio in modern functional materials

C Huang, L Chen - Advanced Materials, 2016 - Wiley Online Library
Materials with negative Poisson's ratio attract considerable attention due to their underlying
intriguing physical properties and numerous promising applications, particularly in stringent …

Innovative molecular design strategies in materials science following the aurophilicity concept

N Mirzadeh, SH Privér, AJ Blake, H Schmidbaur… - Chemical …, 2020 - ACS Publications
The past decade has seen a diverse range of breakthrough inventions that are derived from
gold complexes, including the application of aurophilic interactions in the preparation of …

Giant uniaxial negative thermal expansion in FeZr2 alloy over a wide temperature range

M Xu, Q Li, Y Song, Y Xu, A Sanson, N Shi… - Nature …, 2023 - nature.com
Negative thermal expansion (NTE) alloys possess great practical merit as thermal offsets for
positive thermal expansion due to its metallic properties. However, achieving a large NTE …

Two decades of negative thermal expansion research: where do we stand?

C Lind - Materials, 2012 - mdpi.com
Negative thermal expansion (NTE) materials have become a rapidly growing area of
research over the past two decades. The initial discovery of materials displaying NTE over a …

Giant negative linear compressibility in zinc dicyanoaurate

AB Cairns, J Catafesta, C Levelut, J Rouquette… - Nature materials, 2013 - nature.com
The counterintuitive phenomenon of negative linear compressibility (NLC) is a highly
desirable but rare property exploitable in the development of artificial muscles, actuators and …

Phonons and anomalous thermal expansion behaviour in crystalline solids

R Mittal, MK Gupta, SL Chaplot - Progress in Materials Science, 2018 - Elsevier
Anomalous thermal expansion behaviour of several open frame-work compounds has been
extensively investigated using the techniques of inelastic neutron scattering and lattice …

Exceptionally large positive and negative anisotropic thermal expansion of an organic crystalline material

D Das, T Jacobs, LJ Barbour - Nature Materials, 2010 - nature.com
In general, the relatively modest expansion experienced by most materials on heating is
caused by increasing anharmonic vibrational amplitudes of the constituent atoms, ions or …

Massive Anisotropic Thermal Expansion and Thermo‐Responsive Breathing in Metal–Organic Frameworks Modulated by Linker Functionalization

S Henke, A Schneemann… - Advanced Functional …, 2013 - Wiley Online Library
Functionalized metal–organic frameworks (fu‐MOFs) of general formula [Zn2 (fu‐L) 2dabco]
n show unprecedentedly large uniaxial positive and negative thermal expansion (fu‐L …

Negative thermal expansion in molecular materials

Z Liu, Q Gao, J Chen, J Deng, K Lin… - Chemical …, 2018 - pubs.rsc.org
Negative thermal expansion (NTE), whereby lattices contract upon heating, is of
considerable interest for its wide applications in many fields. Molecular materials have been …