Since Friedrich Wöhler's groundbreaking synthesis of urea in 1828, organic synthesis over
the past two centuries has predominantly relied on the exploration and utilization of …

An asymmetric intramolecular spiro-amination to high steric hindering α-C–H bond of 1, 3-
dicarbonyl via nitrene transfer using inactive aryl azides has been carried out by developing …

Due to their unique design, chiral metal complexes play an important role in asymmetric
synthesis. In this review, we have focused on the design strategy and its applications in …

Cross-coupling catalysts typically react and unite functionally distinct partners via sequential
inner-sphere elementary steps: coordination, migratory insertion, reductive elimination, etc …

Engineered hemoproteins can selectively incorporate nitrogen from nitrene precursors like
hydroxylamine, O-substituted hydroxylamines, and organic azides into organic molecules …

Abstract β‐Tertiary amino acid derivatives constitute one of the most frequently occurring
units in natural products and bioactive molecules. However, the efficient asymmetric …

Multicomponent reactions that involve carbenes with nucleophiles and electrophiles have
demonstrated broad applications in synthetic chemistry. However, because of the high …

Gold-Catalyzed Cascade Cycloisomerization of 3-Allyloxy-1,6-diynes to Cyclopropyl- and
Cyclobutyl-Fused Benzofurans and Chromen-3a(1H)-ols | Organic Letters ACS ACS …

A hitherto unknown class of C4‐symmetric Caryl− Cβ (C3, C8, C13, C18) axially chiral
porphyrins has been synthesized and the application of their iridium (Ir) complexes in …

A synthetic strategy for the catalytic cycloaddition of α-trifluoromethyl-α-diazoketones with
nitriles has been achieved based on cobalt (II) metalloradical catalysis. The easily …