Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …

This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …

The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …

Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …

The Gouterman four-orbital model conceptualizes porphyrin UV–visible spectra as
dominated by four frontier molecular orbitals─ two nearly degenerate HOMOs and two …

Two amphiphilic corroles 5, 10, 15-tris (3-carboxyphenyl) corrole (H3 [m TCPC]) and 5, 10,
15-tris (4-carboxyphenyl) corrole (H3 [p TCPC]) and their gold complexes have been …

A silver β‐octabromo‐meso‐triarylcorrole has been found to exhibit a strongly saddled
geometry, providing the first instance of a strongly saddled corrole complex involving a metal …