Since the prediction of the existence of metallabenzenes in 1979, metallaaromatic chemistry
has developed rapidly, due to its importance in both experimental and theoretical fields …

Conspectus The construction of metal–carbon bonds is one of the most important issues of
organometallic chemistry. However, the chelation of polydentate ligands to a metal via …

We report a general protocol for the convergent synthesis of 1, 4-dicarbonyl Z-alkenes form
alkynes using α-diazo sulfonium triflate and water. The C═ O, C═ C, and C–H bonds are …

Metallaaromatics can be broadly defined as aromatic compounds in which one of the ring
atoms is a transition metal. The metallabenzenes are one important class of these …

Metalloaromatic species are unique and important both experimentally and theoretically.
Significant progress has been made during the past few decades. New aromatic systems …

Over the last decades, the treatment of the large quantities of hypersaline wastewater
generated by conventional industries, inland desalination, and fossil‐fueled power plants …

Metalla‐analogues of archetypal aromatic molecules are attracting ever increasing interest.
Although metallabenzenes (which fall within this class) have been well studied, fused‐ring …

The coordinating atoms in polydentate chelates are primarily heteroatoms. We present the
first examples of pentadentate chelates with all binding atoms of the chelating agent being …

Metal-containing aromatic systems (metalla-aromatics) are unique and important both
experimentally and theoretically. Among metalla-aromatics, six-membered metallabenzenes …

Although the formation of metal–carbon σ bonds is a fundamental principle in
organometallic chemistry, the direct bonding of one organic molecule with one metal center …