Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities

KD Vogiatzis, MV Polynski, JK Kirkland… - Chemical …, 2018 - ACS Publications
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Creating stereocenters within acyclic systems by C–C bond cleavage of cyclopropanes

Y Cohen, A Cohen, I Marek - Chemical Reviews, 2020 - ACS Publications
Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …

Toxicity of metal compounds: knowledge and myths

KS Egorova, VP Ananikov - Organometallics, 2017 - ACS Publications
Organometallic reagents and metal catalysts are used ubiquitously in academia and
industry. Not surprisingly, the biological activity and environmental danger of metal …

Parahydrogen‐based hyperpolarization for biomedicine

JB Hövener, AN Pravdivtsev, B Kidd… - Angewandte Chemie …, 2018 - Wiley Online Library
Magnetic resonance (MR) is one of the most versatile and useful physical effects used for
human imaging, chemical analysis, and the elucidation of molecular structures. However, its …

Improvement of quality of 3D printed objects by elimination of microscopic structural defects in fused deposition modeling

EG Gordeev, AS Galushko, VP Ananikov - PloS one, 2018 - journals.plos.org
Additive manufacturing with fused deposition modeling (FDM) is currently optimized for a
wide range of research and commercial applications. The major disadvantage of FDM …

Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Organofluorine chemistry: Promising growth areas and challenges

LV Politanskaya, GA Selivanova… - Russian Chemical …, 2019 - iopscience.iop.org
Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

Multiple annulations of inert C (sp 2)–H bonds with alkynes

A Saha, M Shankar, S Sau, AK Sahoo - Chemical Communications, 2022 - pubs.rsc.org
Transition-metal catalyzed directing group (DG) assisted annulation of inert C–H bonds
leads to the formation of complex molecular frameworks from readily accessible substrates …

[HTML][HTML] Acetylene in organic synthesis: Recent progress and new uses

VV Voronin, MS Ledovskaya, AS Bogachenkov… - Molecules, 2018 - mdpi.com
Recent progress in the leading synthetic applications of acetylene is discussed from the
prospect of rapid development and novel opportunities. A diversity of reactions involving the …

Organic and hybrid molecular systems

VP Ananikov, EA Khokhlova, MP Egorov… - Mendeleev …, 2015 - Elsevier
The design of functional organic and hybrid molecular systems has shown outstanding
recent growth and is a high priority in the development of new technologies and novel …