Recent advances in the chemistry of isolable carbene analogues with group 13–15 elements
Carbenes (R2C:), compounds with a divalent carbon atom containing only six valence shell
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
Reversible hydrosilane addition to pyridines enabled by low-coordinate Ca (ii) and Yb (ii) hydrides
AN Selikhov, MA Bogachev, YV Nelyubina… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The reactions of amides [tBu2CarbAr2] MN (SiMe3) 2 (THF)(M= Ca (5), Yb (6)) and
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …
N-heterocyclic germylenes and stannylenes: Synthesis, reactivity and catalytic application in a nutshell
R Dasgupta, S Khan - Advances in Organometallic Chemistry, 2020 - Elsevier
Recent years have witnessed a tremendous growth in the area of heavier tetrelylenes, eg,
silylenes, germylenes and stannylenes. However, germylenes and stannylenes are quite …
silylenes, germylenes and stannylenes. However, germylenes and stannylenes are quite …
Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides
J Böserle, G Zhigulin, S Ketkov, R Jambor… - Dalton …, 2018 - pubs.rsc.org
The reactions of the boraquanidinato germylene (i-Pr) 2NB (NDmp) 2Ge (1)(Dmp= 2, 6-
Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while …
Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while …
Germylone-bridged bimetallic Ir and Rh complexes
The reactions of germylone 1 with one equivalent of [M (COD) Cl] 2 (M= Ir, Rh) afforded the
germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and …
germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and …
Reduction properties of germanium dichloride with respect to the redox-active monoiminoacenaphtenone dpp-mian
AN Lukoyanov, YV Zvereva, GY Zhigulin… - Journal of Structural …, 2023 - Springer
Reaction of germanium dichloride [GeCl2 (dioxane)] with 2-(2, 6-diisopropylphenyl-imino)
acenaphthylene-1-one (dpp-MIAN) leads to the reduction of dpp-MIAN and subsequent …
acenaphthylene-1-one (dpp-MIAN) leads to the reduction of dpp-MIAN and subsequent …
Electronic Structures of Alaninehydroximate 15-Metallacrowns-5 with Lanthanum (III), Cerium (III), and Praseodymium (III) Ions
GY Zhigulin - Journal of Structural Chemistry, 2024 - Springer
Molecular and electronic structures of heterobimetallic Ln (III)–Cu (II) C 5-symmetric
metallamacrocycles (15-metallacrowns-5) bearing L-α-alaninehydroximate (Alaha) ligands …
metallamacrocycles (15-metallacrowns-5) bearing L-α-alaninehydroximate (Alaha) ligands …
Insertion of the N, B, N-chelated germylene into P-Cl Bond (s) in selected chlorophosphines
J Böserle, R Jambor, A Růžička, L Dostál - Journal of Organometallic …, 2018 - Elsevier
The reaction of the N, B, N-chelated germylene [(i-Pr) 2 NB (NDmp) 2] Ge (1)(where Dmp= 2,
6-Me 2 C 6 H 3) with Ph 2 PCl in 1: 1 stoichiometric ratio led to a smooth insertion into the P …
6-Me 2 C 6 H 3) with Ph 2 PCl in 1: 1 stoichiometric ratio led to a smooth insertion into the P …
Reactivity of boraguanidinato germylenes toward carbonyl compounds and isocyanides: C–O, C–F and C–N bond activation
J Böserle, R Jambor, A Růžička, M Erben… - Dalton Transactions, 2020 - pubs.rsc.org
The reactions of two equivalents of germylene [(i-Pr) 2NB (N-2, 6-Me2C6H3) 2] Ge (1) with
carbonyl compounds RC (O) R′ resulted in carbonyl functionality activation and the …
carbonyl compounds RC (O) R′ resulted in carbonyl functionality activation and the …
Spirocyclic germanes via transannular insertion reactions of vinyl germylenes into Si–Si bonds
M Walewska, J Baumgartner, C Marschner… - Dalton …, 2018 - pubs.rsc.org
The reactions of two cyclic germylene phosphane adducts with monosubstituted acetylenes
caused the formation of spirocyclic germanes, which is postulated to occur by double …
caused the formation of spirocyclic germanes, which is postulated to occur by double …