Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes

M Crespo, M Martinez, SM Nabavizadeh… - Coordination Chemistry …, 2014 - Elsevier
The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

The history of organoplatinum chemistry in Iran: 40-year research

RB Aghakhanpour, S Paziresh… - Journal of the Iranian …, 2020 - Springer
This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his
working years in Shiraz University, Chemistry Department, Organometallic Chemistry …

Photophysical and DFT studies on cycloplatinated complexes: modification in luminescence properties by expanding of π-conjugated systems

M Jamshidi, SM Nabavizadeh, HR Shahsavari… - RSC …, 2015 - pubs.rsc.org
To investigate the factors influencing the luminescent properties of cycloplatinated
complexes containing aryl and SMe2 ligands, a detailed study of the photophysical and …

Cyclometalated C^ C* Platinum (IV) NHC Complexes

T Riesebeck, A Tronnier, T Strassner - Inorganic Chemistry, 2024 - ACS Publications
We present a previously unknown series of cyclometalated platinum (IV) NHC complexes,
obtained by oxidative addition of iodine, iodomethane, and different benzyl bromides to …

High-Valent Pyrazolate-Bridged Platinum Complexes: A Joint Experimental and Theoretical Study

L Arnal, D Escudero, S Fuertes, A Martin… - Inorganic …, 2022 - ACS Publications
Complexes [{Pt (C^ C*)(μ-pz)} 2](HC^ C* A= 1-(4-(ethoxycarbonyl) phenyl)-3-methyl-1 H-
imidazol-2-ylidene 1a, HC^ C* B= 1-phenyl-3-methyl-1 H-imidazol-2-ylidene 1b) react with …

Oxidation of Half-Lantern Pt2(II,II) Compounds by Halocarbons. Evidence of Dioxygen Insertion into a Pt(III)–CH3 Bond

V Sicilia, M Baya, P Borja, A Martín - Inorganic Chemistry, 2015 - ACS Publications
The half-lantern compound [{Pt (bzq)(μ-N^ S)} 2](1)[bzq= benzo [h] quinoline, HN^ S= 2-
mercaptopyrimidine (C4H3N2HS)] reacts with CH3I and haloforms CHX3 (X= Cl, Br, I) to …

Oxidation of a rollover cycloplatinated (ii) dimer by MeI: A kinetic study

RB Aghakhanpour, M Rashidi, FN Hosseini, F Raoof… - RSC …, 2015 - pubs.rsc.org
The known rollover cycloplatinated (II) complex [Pt2Me2 (PPh3) 2 (μ-bpy-2H)], 1, in which
bpy-2H acts as a bridging rollover ligand, was reacted with MeI to give a new binuclear …

A kinetic approach to carbon–iodide bond activation by rollover cycloplatinated (II) complexes containing monodentate phosphine ligands

RB Aghakhanpour, SM Nabavizadeh… - Journal of …, 2015 - Elsevier
New rollover cyclometalated platinum (II) complex [PtMe (bpy-H)(PPh 2 Me)](bpy-H= κ 2 N,
C-2, 2′-bipyridine) was synthesized by the reaction of [PtMe (bpy-H)(DMSO)] with 1 equiv …

Metal–Metal Cooperation in the Oxidation of a Flapping Platinum Butterfly by Haloforms: Experimental and Theoretical Evidence

V Sicilia, L Arnal, S Fuertes, A Martín… - Inorganic Chemistry, 2020 - ACS Publications
The model 1-DFT for the butterfly complex [{Pt (C∧ C*)(μ-pz)} 2](1; HC∧ C*= 1-(4-
(ethoxycarbonyl) phenyl)-3-methyl-1 H-imidazol-2-ylidene) shows two minima in the …

Bis (diphenylphosphino) acetylene as bifunctional ligand in cycloplatinated complexes: Synthesis, characterization, crystal structures and mechanism of MeI oxidative …

SM Nabavizadeh, H Sepehrpour, R Kia… - Journal of …, 2013 - Elsevier
Binuclear cycloplatinated (II) complexes with general formula of [Pt 2 Me 2 (CˆN) 2 (μ-
dppac)],(1, CˆN= deprotonated 2-phenylpyridine (ppy); 2, CˆN= deprotonated benzo {h} …