Redox-active ligands–a viable route to reactive main group metal compounds

GG Briand - Dalton Transactions, 2023 - pubs.rsc.org
Anionic redox-active ligands such as o-amidophenolates, catecholates, dithiolenes, 1, 2-
benzendithiolates, 2-amidobenzenethiolates, reduced α-diimines, ferrocenyl and …

Expanding the Scope of Aluminum Chemistry with Noninnocent Ligands

LWT Parsons, LA Berben - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism

MA Hay, JT Janetzki, VJ Kumar, RW Gable… - Inorganic …, 2022 - ACS Publications
Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing
a range of molecular materials for sensing, memory, and optoelectronic applications …

Group 13 ion coordination to pyridyl models NAD+ reduction potentials

LWT Parsons, JC Fettinger, LA Berben - Chemical Communications, 2023 - pubs.rsc.org
N-alkylation and N-metallation of pyridine are explored herein to understand how metal-
ligand complexes can model NAD+ redox chemistry. Syntheses of substituted …

Controlling intramolecular and intermolecular electronic coupling of radical ligands in a series of cobaltoviologen complexes

BJO Kessler, IF Mansoor, DI Wozniak… - Journal of the …, 2023 - ACS Publications
Controlling electronic coupling between multiple redox sites is of interest for tuning the
electronic properties of molecules and materials. While classic mixed-valence (MV) systems …

Syntheses of square planar gallium complexes and a proton NMR correlation probing metalloaromaticity

TM Bass, CR Carr, TJ Sherbow, JC Fettinger… - Inorganic …, 2020 - ACS Publications
Syntheses of square planar (SP) coordination complexes of gallium (III) are reported herein.
Using the pyridine diimine ligand (PDI), we prepared both (PDI2–) GaH (4) and (PDI2–) …

Cationic indium catalysts for ring opening polymerization: tuning reactivity with hemilabile ligands

C Goonesinghe, H Roshandel, C Diaz, HJ Jung… - Chemical …, 2020 - pubs.rsc.org
This is a comprehensive study of the effects of rationally designed hemilabile ligands on the
stability, reactivity, and change in catalytic behavior of indium complexes. We report cationic …

Enabling Valence Delocalization in Iron (III) Macrocyclic Complexes through Ring Unsaturation

RA Clendening, SS Delancey, AT Poore… - Inorganic …, 2023 - ACS Publications
The complexes [FeIII (HMC)(C2DMA) 2] CF3SO3 ([2] OTf) and [FeIII (HMTI)(C2Y) 2] CF3SO3
([3a–c] OTf) have been prepared and thoroughly characterized (HMC= 5, 5, 7, 12, 12, 14 …

[HTML][HTML] Harnessing electrostatic interactions for enhanced conductivity in metal-organic frameworks

AA Zhang, X Cheng, X He, W Liu, S Deng, R Cao… - Research, 2021 - spj.science.org
The poor electrical conductivity of metal-organic frameworks (MOFs) has been a stumbling
block for its applications in many important fields. Therefore, exploring a simple and effective …

2, 6-Diiminopyridine complexes of group 2 metals: synthesis, characterisation and redox behaviour

MJC Dawkins, AN Simonov, C Jones - Dalton Transactions, 2020 - pubs.rsc.org
Treatment of the 2, 6-diiminopyridine, NC5H3 {C (Ph) N (Dip)} 2-2, 6 (PhDimpy, Dip= 2, 6-
diisopropylphenyl) with [MgI2 (OEt2) 2] gives the adduct complex [(PhDimpy) MgI2] in which …