Confined crystallization of polymeric materials

RM Michell, AJ Müller - Progress in Polymer Science, 2016 - Elsevier
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …

Polyolefins based crystalline block copolymers: Ordered nanostructures from control of crystallization

C De Rosa, R Di Girolamo, A Malafronte, M Scoti… - Polymer, 2020 - Elsevier
In this paper the morphologies and crystallization properties of crystalline block copolymers
are reviewed. The equilibrium morphologies expected in crystalline-amorphous diblock …

Chemically crosslinked crystalline thermoplastic polyolefin elastomer with good elasticity and improved thermo-mechanical properties

Y Zhao, Y Ma, Y Xiong, T Qin, Y Zhu, H Deng, J Qin… - Polymer, 2022 - Elsevier
Due to mechanical α-relaxation process, olefin block copolymer (OBC) has a limited heat
resistance and thermo-mechanical property. In this work, peroxide-induced melt crosslinking …

Crystallization Kinetics of Crystalline–Crystalline and Crystalline–Amorphous Block Copolymers of Linear Polyethylene and Isotactic Polypropylene

A Cicolella, M Scoti, G Talarico, AJ Müller… - …, 2024 - ACS Publications
Crystalline–amorphous diblock copolymers (BCPs) comprising crystalline blocks of isotactic
polypropylene (iPP) or polyethylene (PE) linked to amorphous blocks of random ethylene …

Tailoring the Properties of Chemically Recyclable Polyethylene‐Like Multiblock Polymers by Modulating the Branch Structure

Y Zhao, EM Rettner, ME Battson, Z Hu… - Angewandte Chemie …, 2024 - Wiley Online Library
Developing plastics that fill the need of polyolefins yet are more easily recyclable is a critical
need to address the plastic waste crisis. However, most efforts in this vein have focused on …

Extending the high-throughput experimentation (HTE) approach to catalytic olefin polymerizations: From catalysts to materials

A Vittoria, G Urciuoli, S Costanzo, D Tammaro… - …, 2022 - ACS Publications
In this study, a state-of-the-art high-throughput experimentation (HTE) workflow for catalytic
olefin polymerization, covering an unprecedented wide part of the polymer knowledge and …

In-depth analysis of the nonuniform chain microstructure of multiblock copolymers from chain-shuttling polymerization

G Urciuoli, A Vittoria, G Talarico, D Luise… - …, 2021 - ACS Publications
The nonuniform molecular architecture of ethylene/1-octene multiblock copolymers (O-
MBCs) synthesized by the chain shuttling technology is investigated. The samples consist of …

Thermal fractionation of ethylene/1-octene multiblock copolymers from chain shuttling polymerization

G Urciuoli, O Ruiz de Ballesteros, R Cipullo… - …, 2022 - ACS Publications
Ethylene/1-octene statistical multiblock copolymers (OMBCs) consisting of the alternation of
crystalline, hard blocks and amorphous, soft blocks, with≈ 0.5 and 20 mol% of 1-octene …

Nucleation of Poly (lactide) on the Surface of Different Fibers

B Wang, T Wen, X Zhang, A Tercjak, X Dong… - …, 2019 - ACS Publications
The nucleation process of poly (lactide)(PLA) on a series of fibers was studied by means of
in situ polarized optical microscope during crystallization. Several synthetic and natural …

Synthesis of Statistical Multiblock Copolymers through Chain Shuttling Copolymerization with a Thermomechanical Switch Behavior

A Vittoria, G Urciuoli, S Costanzo, V Ianniello… - …, 2024 - ACS Publications
A high-throughput experimentation (HTE) approach is adopted for the synthesis of a special
class of elastomeric polyolefins with a tailored thermomechanical response …