Development and advancement of iridium (III)-based complexes for photocatalytic hydrogen evolution

DN Tritton, FK Tang, GB Bodedla, FW Lee… - Coordination Chemistry …, 2022 - Elsevier
Among the vast array of transition metal complexes which have been previously reported,
organometallic compounds based on iridium (III) and relevant metal complexes have been …

Molecular catalysts of Co, Ni, Fe, and Mo for hydrogen generation in artificial photosynthetic systems

WT Eckenhoff - Coordination Chemistry Reviews, 2018 - Elsevier
Driven by population and quality of living increases, the global consumption of energy is
expected to dramatically increase over the course of the century. To avoid meeting this …

Exploring the phototoxicity of hypoxic active iridium (III)-based sensitizers in 3D tumor spheroids

R Bevernaegie, B Doix, E Bastien… - Journal of the …, 2019 - ACS Publications
Among all molecules developed for anticancer therapies, photodynamic therapeutic agents
have a unique profile. Their maximal activity is specifically triggered in tumors by light, and …

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

A Mazzeo, S Santalla, C Gaviglio, F Doctorovich… - Inorganica Chimica …, 2021 - Elsevier
The rich chemistry, low cost and availability offered by first-row transition metals have
inspired many researchers to focus on the design, preparation and testing of a wide plethora …

Improved visible light absorption of potent iridium (III) photo-oxidants for excited-state electron transfer chemistry

R Bevernaegie, SAM Wehlin, EJ Piechota… - Journal of the …, 2020 - ACS Publications
Three iridium photosensitizers,[Ir (dCF3ppy) 2 (N–N)]+, where N–N is 1, 4, 5, 8-
tetraazaphenanthrene (TAP), pyrazino [2, 3-a] phenazine (pzph), or benzo [a] pyrazino [2, 3 …

The odyssey of cobaloximes for catalytic H 2 production and their recent revival with enzyme-inspired design

D Dolui, S Khandelwal, P Majumder… - Chemical …, 2020 - pubs.rsc.org
Cobaloxime complexes gained attention for their intrinsic ability of catalytic H2 production
despite their initial emergence as a vitamin B12 model. The simple, robust, and synthetically …

Efficient red-light-driven hydrogen evolution with an anthraquinone organic dye

M Ming, H Yuan, S Yang, Z Wei, Q Lei… - Journal of the …, 2022 - ACS Publications
The direct utilization of the full solar spectrum to obtain renewable fuels remains a challenge
because the conversion of the low-energy light (red and near-infrared) is difficult. Current …

Cobaloxime complex salts: synthesis, patterning on carbon nanomembranes and heterogeneous hydrogen evolution studies

E Oswald, AL Gaus, J Kund, M Küllmer… - … A European Journal, 2021 - Wiley Online Library
Cobaloximes are promising, earth‐abundant catalysts for the light‐driven hydrogen
evolution reaction (HER). Typically, these cobalt (III) complexes are prepared in situ or …

Recent progress on the design and development of diaminotriazine based molecular catalysts for light-driven hydrogen production

S Rajak, NN Vu, P Kaur, A Duong… - Coordination Chemistry …, 2022 - Elsevier
With the depletion of fossil fuels and an increase in global warming, developing clean and
sustainable energy resources is imperative. Among the different possible eco-friendly …

Merging two functions in a single Rh catalyst system: bimodular conjugate for light-induced oxidative coupling

J Kim, D Kim, S Chang - Journal of the American Chemical …, 2020 - ACS Publications
A single molecular rhodium catalyst system (PC2-Cp# RhIII) bearing two functional domains
for both photosensitization and C–H carbometalation was designed to enable an …