Metal nanoclusters: from fundamental aspects to electronic properties and optical applications

R Antoine, M Broyer, P Dugourd - Science and Technology of …, 2023 - Taylor & Francis
Monolayer-protected noble metal clusters, also called nanoclusters, can be produced with
the atomic precision and in large-scale quantity and are playing an increasingly important …

Spin coupling and orbital angular momentum quenching in free iron clusters

M Niemeyer, K Hirsch, V Zamudio-Bayer… - Physical review …, 2012 - APS
Magnetic spin and orbital moments of size-selected free iron cluster ions Fe n+(n= 3–20)
have been determined via x-ray magnetic circular dichroism spectroscopy. Iron atoms within …

Visible and ultraviolet spectroscopy of gas phase protein ions

R Antoine, P Dugourd - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
Optical spectroscopy has contributed enormously to our knowledge of the structure and
dynamics of atoms and molecules and is now emerging as a cornerstone of the gas phase …

X-ray spectroscopy on size-selected clusters in an ion trap: from the molecular limit to bulk properties

K Hirsch, JT Lau, P Klar, A Langenberg… - Journal of Physics B …, 2009 - iopscience.iop.org
An experiment was designed to perform x-ray and VUV spectroscopy on size-selected
clusters in the gas phase. Using a radio frequency ion trap and a quadrupole mass filter …

The fluorescence properties of cationic rhodamine B in the gas phase

SK Sagoo, RA Jockusch - Journal of Photochemistry and Photobiology A …, 2011 - Elsevier
Studying the photophysical properties of molecules in the gasphase can be advantageous,
because it reduces the complexity of the system examined by eliminating effects due to …

Photodestruction Action Spectroscopy of Silver Cluster Anions, AgN (N = 3–19), with a Linear Ion Trap: Observation of Bound Excited States above the …

S Kawamura, M Yamaguchi, S Kono… - The Journal of …, 2023 - ACS Publications
Electron detachment thresholds of metal cluster anions, MN–, are a few electron volts. The
excess electron is therefore detached by visible or ultraviolet light, which also creates low …

Cold CAS ion trap–22 pole trap with ring electrodes for astrochemistry

P Jusko, M Jiménez-Redondo, P Caselli - Molecular Physics, 2024 - Taylor & Francis
The enhancement of a cryogenic radio frequency 22 pole trap instrument by the addition of
ring electrodes is presented in detail. The ring electrodes tightly surround the poles and only …

Magnetic moments of chromium-doped gold clusters: The anderson impurity model in finite systems

K Hirsch, V Zamudio-Bayer, A Langenberg… - Physical review …, 2015 - APS
The magnetic moment of a single impurity atom in a finite free electron gas is studied in a
combined x-ray magnetic circular dichroism spectroscopy, charge transfer multiplet …

Improvement of reflectron time-of-flight mass spectrometer for better convergence of ion beam

T Handa, T Horio, M Arakawa, A Terasaki - International Journal of Mass …, 2020 - Elsevier
Reflectron time-of-flight mass spectrometer (RTOF-MS) is a powerful tool to achieve high
resolution in mass analysis of various ions. As it is often supposed that analyte ions are …

Direct observation of high-spin states in manganese dimer and trimer cations by x-ray magnetic circular dichroism spectroscopy in an ion trap

V Zamudio-Bayer, K Hirsch, A Langenberg… - The Journal of …, 2015 - pubs.aip.org
The electronic structure and magnetic moments of free Mn 2+ and Mn 3+ are characterized
by 2p x-ray absorption and x-ray magnetic circular dichroism spectroscopy in a cryogenic …