Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Advanced porous adsorbents for radionuclides elimination

M Hao, Y Liu, W Wu, S Wang, X Yang, Z Chen, Z Tang… - EnergyChem, 2023 - Elsevier
With the rapid development of nuclear industry, effective management of nuclear waste and
oversight of nuclear fuel cycle are critical. Radionuclides such as uranium (U), plutonium …

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Z Liang, HY Wang, H Zheng, W Zhang… - Chemical Society …, 2021 - pubs.rsc.org
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Trace to the source: self‐tuning of MOF photocatalysts

Z Qian, R Zhang, Y Xiao, H Huang… - Advanced Energy …, 2023 - Wiley Online Library
Benefitting from ultra‐high porosity, large specific surface area (SSA), and rich active sites,
metal–organic frameworks (MOFs) have emerged as a star material in energy and …

Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis

W Xu, Y Wu, W Gu, D Du, Y Lin, C Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

A historical perspective on porphyrin-based metal–organic frameworks and their applications

X Zhang, MC Wasson, M Shayan… - Coordination chemistry …, 2021 - Elsevier
Porphyrins are important molecules widely found in nature in the form of enzyme active sites
and visible light absorption units. Recent interest in using these functional molecules as …

Metal–organic frameworks based on multicarboxylate linkers

H Ghasempour, KY Wang, JA Powell… - Coordination Chemistry …, 2021 - Elsevier
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs

F Ambroz, TJ Macdonald, V Martis, IP Parkin - Small methods, 2018 - Wiley Online Library
Surface area determination with the Brunauer–Emmett–Teller (BET) method is a widely
used characterization technique for metal–organic frameworks (MOFs). Since these …

Light-Promoted CO2 Conversion from Epoxides to Cyclic Carbonates at Ambient Conditions over a Bi-Based Metal–Organic Framework

G Zhai, Y Liu, L Lei, J Wang, Z Wang, Z Zheng… - Acs …, 2021 - ACS Publications
For traditional cycloaddition reaction between CO2 and epoxide, high temperature and high
pressure are usually needed. In this work, we introduce Lewis acid Bi atom into the …